31P N.M.R. studies on trialkylphosphinegold(I) derivatives of ruthenium carbide clusters: Synthesis and x-ray crystal structures of [Ru 6C(CO)16(AuPMePh2)2] and [Ru 5WC(CO)17(AuPEt3)2]

Steven R. Bunkhall; H. Diane Holden; Brian F.G. Johnson; Jack Lewis; Geoff N. Pain; Paul R. Raithby; Michael J. Taylor

doi:10.1039/c39840000025

³¹P N.M.R. studies on trialkylphosphinegold(I) derivatives of ruthenium carbide clusters: Synthesis and x-ray crystal structures of [Ru ₆C(CO)₁₆(AuPMePh₂)₂] and [Ru ₅WC(CO)₁₇(AuPEt₃)₂]

Steven R. Bunkhall, H. Diane Holden, Brian F.G. Johnson, Jack Lewis, Geoff N. Pain, Paul R. Raithby, Michael J. Taylor

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of the anions [Ru₆C(CO)₁₆]^2- and [Ru₅WC(CO)₁₇]^2- with ClAuPR₃ (R = alkyl, aryl) yields [Ru₆C(CO)₁₆(AuPR₃) ₂] and [Ru₅WC(CO)₁₇(AuPR₃) ₂], respectively; X-ray crystallography has shown that the two gold atoms adopt a different geometry in each case and subsequent low-temperature ³¹P{¹H} n.m.r. studies have shown that these compounds exist as isomeric species in solution.

Original language	English
Pages (from-to)	25-27
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/c39840000025
Publication status	Published - 1984

ASJC Scopus subject areas

Molecular Medicine

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Bunkhall, S. R., Holden, H. D., Johnson, B. F. G., Lewis, J., Pain, G. N., Raithby, P. R., & Taylor, M. J. (1984). ³¹P N.M.R. studies on trialkylphosphinegold(I) derivatives of ruthenium carbide clusters: Synthesis and x-ray crystal structures of [Ru ₆C(CO)₁₆(AuPMePh₂)₂] and [Ru ₅WC(CO)₁₇(AuPEt₃)₂]. Journal of the Chemical Society, Chemical Communications, (1), 25-27. https://doi.org/10.1039/c39840000025

³¹P N.M.R. studies on trialkylphosphinegold(I) derivatives of ruthenium carbide clusters: Synthesis and x-ray crystal structures of [Ru ₆C(CO)₁₆(AuPMePh₂)₂] and [Ru ₅WC(CO)₁₇(AuPEt₃)₂]. / Bunkhall, Steven R.; Holden, H. Diane; Johnson, Brian F.G. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 1, 1984, p. 25-27.

Research output: Contribution to journal › Article › peer-review

Bunkhall, SR, Holden, HD, Johnson, BFG, Lewis, J, Pain, GN, Raithby, PR & Taylor, MJ 1984, '³¹P N.M.R. studies on trialkylphosphinegold(I) derivatives of ruthenium carbide clusters: Synthesis and x-ray crystal structures of [Ru ₆C(CO)₁₆(AuPMePh₂)₂] and [Ru ₅WC(CO)₁₇(AuPEt₃)₂]', Journal of the Chemical Society, Chemical Communications, no. 1, pp. 25-27. https://doi.org/10.1039/c39840000025

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title = "31P N.M.R. studies on trialkylphosphinegold(I) derivatives of ruthenium carbide clusters: Synthesis and x-ray crystal structures of [Ru 6C(CO)16(AuPMePh2)2] and [Ru 5WC(CO)17(AuPEt3)2]",

abstract = "Reaction of the anions [Ru6C(CO)16]2- and [Ru5WC(CO)17]2- with ClAuPR3 (R = alkyl, aryl) yields [Ru6C(CO)16(AuPR3) 2] and [Ru5WC(CO)17(AuPR3) 2], respectively; X-ray crystallography has shown that the two gold atoms adopt a different geometry in each case and subsequent low-temperature 31P\{1H\} n.m.r. studies have shown that these compounds exist as isomeric species in solution.",

author = "Bunkhall, \{Steven R.\} and Holden, \{H. Diane\} and Johnson, \{Brian F.G.\} and Jack Lewis and Pain, \{Geoff N.\} and Raithby, \{Paul R.\} and Taylor, \{Michael J.\}",

year = "1984",

doi = "10.1039/c39840000025",

language = "English",

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journal = "Journal of the Chemical Society, Chemical Communications",

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T2 - Synthesis and x-ray crystal structures of [Ru 6C(CO)16(AuPMePh2)2] and [Ru 5WC(CO)17(AuPEt3)2]

AU - Bunkhall, Steven R.

AU - Holden, H. Diane

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Pain, Geoff N.

AU - Raithby, Paul R.

AU - Taylor, Michael J.

PY - 1984

Y1 - 1984

N2 - Reaction of the anions [Ru6C(CO)16]2- and [Ru5WC(CO)17]2- with ClAuPR3 (R = alkyl, aryl) yields [Ru6C(CO)16(AuPR3) 2] and [Ru5WC(CO)17(AuPR3) 2], respectively; X-ray crystallography has shown that the two gold atoms adopt a different geometry in each case and subsequent low-temperature 31P{1H} n.m.r. studies have shown that these compounds exist as isomeric species in solution.

AB - Reaction of the anions [Ru6C(CO)16]2- and [Ru5WC(CO)17]2- with ClAuPR3 (R = alkyl, aryl) yields [Ru6C(CO)16(AuPR3) 2] and [Ru5WC(CO)17(AuPR3) 2], respectively; X-ray crystallography has shown that the two gold atoms adopt a different geometry in each case and subsequent low-temperature 31P{1H} n.m.r. studies have shown that these compounds exist as isomeric species in solution.

UR - https://www.scopus.com/pages/publications/0042759851

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DO - 10.1039/c39840000025

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AN - SCOPUS:0042759851

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 1

ER -

³¹P N.M.R. studies on trialkylphosphinegold(I) derivatives of ruthenium carbide clusters: Synthesis and x-ray crystal structures of [Ru ₆C(CO)₁₆(AuPMePh₂)₂] and [Ru ₅WC(CO)₁₇(AuPEt₃)₂]

Abstract

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