Sulfides tethered to oxazolines: Ligands for enantioselective catalysis

G.J. Dawson; C.G. Frost; C.J. Martin; Jonathan M J Williams; S.J. Coote

doi:10.1016/S0040-4039(00)61568-X

Sulfides tethered to oxazolines: Ligands for enantioselective catalysis

G.J. Dawson, C.G. Frost, C.J. Martin, Jonathan M J Williams, S.J. Coote

Loughborough University

Research output: Contribution to journal › Article › peer-review

Abstract

Sulfides tethered to oxazolines function as effective ligands for palladium catalysed allylic substitution, affording good to excellent levels of enantioselectivity (56 to >96% ee). Both the tether length between the nitrogen and sulfur atoms and also the nature of the sulfide have been shown to affect the performance of these ligands.

Original language	English
Pages (from-to)	7793-7796
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	48
DOIs	https://doi.org/10.1016/S0040-4039(00)61568-X
Publication status	Published - 26 Nov 1993

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title = "Sulfides tethered to oxazolines: Ligands for enantioselective catalysis",

abstract = "Sulfides tethered to oxazolines function as effective ligands for palladium catalysed allylic substitution, affording good to excellent levels of enantioselectivity (56 to >96\% ee). Both the tether length between the nitrogen and sulfur atoms and also the nature of the sulfide have been shown to affect the performance of these ligands.",

author = "G.J. Dawson and C.G. Frost and C.J. Martin and Williams, \{Jonathan M J\} and S.J. Coote",

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T1 - Sulfides tethered to oxazolines

T2 - Ligands for enantioselective catalysis

AU - Dawson, G.J.

AU - Frost, C.G.

AU - Martin, C.J.

AU - Williams, Jonathan M J

AU - Coote, S.J.

PY - 1993/11/26

Y1 - 1993/11/26

N2 - Sulfides tethered to oxazolines function as effective ligands for palladium catalysed allylic substitution, affording good to excellent levels of enantioselectivity (56 to >96% ee). Both the tether length between the nitrogen and sulfur atoms and also the nature of the sulfide have been shown to affect the performance of these ligands.

AB - Sulfides tethered to oxazolines function as effective ligands for palladium catalysed allylic substitution, affording good to excellent levels of enantioselectivity (56 to >96% ee). Both the tether length between the nitrogen and sulfur atoms and also the nature of the sulfide have been shown to affect the performance of these ligands.

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UR - http://dx.doi.org/10.1016/S0040-4039(00)61568-X

U2 - 10.1016/S0040-4039(00)61568-X

DO - 10.1016/S0040-4039(00)61568-X

M3 - Article

AN - SCOPUS:0027384278

SN - 0040-4039

VL - 34

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EP - 7796

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 48

ER -

Sulfides tethered to oxazolines: Ligands for enantioselective catalysis

Abstract

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