Sulfides tethered to oxazolines

Ligands for enantioselective catalysis

G.J. Dawson, C.G. Frost, C.J. Martin, Jonathan M J Williams, S.J. Coote

Research output: Contribution to journalArticle

Abstract

Sulfides tethered to oxazolines function as effective ligands for palladium catalysed allylic substitution, affording good to excellent levels of enantioselectivity (56 to >96% ee). Both the tether length between the nitrogen and sulfur atoms and also the nature of the sulfide have been shown to affect the performance of these ligands.
Original languageEnglish
Pages (from-to)7793-7796
Number of pages4
JournalTetrahedron Letters
Volume34
Issue number48
DOIs
Publication statusPublished - 26 Nov 1993

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Sulfides
Catalysis
Ligands
Enantioselectivity
Palladium
Sulfur
Substitution reactions
Nitrogen
Atoms

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Sulfides tethered to oxazolines : Ligands for enantioselective catalysis. / Dawson, G.J.; Frost, C.G.; Martin, C.J.; Williams, Jonathan M J; Coote, S.J.

In: Tetrahedron Letters, Vol. 34, No. 48, 26.11.1993, p. 7793-7796.

Research output: Contribution to journalArticle

Dawson, G.J. ; Frost, C.G. ; Martin, C.J. ; Williams, Jonathan M J ; Coote, S.J. / Sulfides tethered to oxazolines : Ligands for enantioselective catalysis. In: Tetrahedron Letters. 1993 ; Vol. 34, No. 48. pp. 7793-7796.
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