Sulfides tethered to oxazolines: Ligands for enantioselective catalysis

G.J. Dawson, C.G. Frost, C.J. Martin, Jonathan M J Williams, S.J. Coote

Research output: Contribution to journalArticle

Abstract

Sulfides tethered to oxazolines function as effective ligands for palladium catalysed allylic substitution, affording good to excellent levels of enantioselectivity (56 to >96% ee). Both the tether length between the nitrogen and sulfur atoms and also the nature of the sulfide have been shown to affect the performance of these ligands.
LanguageEnglish
Pages7793-7796
Number of pages4
JournalTetrahedron Letters
Volume34
Issue number48
DOIs
StatusPublished - 26 Nov 1993

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Sulfides
Catalysis
Ligands
Enantioselectivity
Palladium
Sulfur
Substitution reactions
Nitrogen
Atoms

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Sulfides tethered to oxazolines : Ligands for enantioselective catalysis. / Dawson, G.J.; Frost, C.G.; Martin, C.J.; Williams, Jonathan M J; Coote, S.J.

In: Tetrahedron Letters, Vol. 34, No. 48, 26.11.1993, p. 7793-7796.

Research output: Contribution to journalArticle

Dawson, G.J. ; Frost, C.G. ; Martin, C.J. ; Williams, Jonathan M J ; Coote, S.J. / Sulfides tethered to oxazolines : Ligands for enantioselective catalysis. In: Tetrahedron Letters. 1993 ; Vol. 34, No. 48. pp. 7793-7796.
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