Sulfide accumulation and sensing based on electrochemical processes in microdroplets of N'-[4-(dihexylamino)phenyl]-N1,N4,N4-trihexyl- 1,4-phenylenediamine

Frank Marken; Alastair Blythe; Richard G. Compton; Steven D. Bull; Stephen G. Davies

doi:10.1039/a905278j

Sulfide accumulation and sensing based on electrochemical processes in microdroplets of N'-[4-(dihexylamino)phenyl]-N¹,N⁴,N⁴-trihexyl- 1,4-phenylenediamine

Frank Marken, Alastair Blythe, Richard G. Compton, Steven D. Bull, Stephen G. Davies

Research output: Contribution to journal › Article

25 Citations (Scopus)

Abstract

Electroanalytical sulfide detection via oxidation of N¹-[4-(dihexylamino)phenyl]-N¹,N⁴,N⁴-trihexyl-1,4-phenylene diamine (DPTPD) deposited in form of microdroplets onto basal plane pyrolytic graphite electrodes immersed in aqueous 0.1 M NaClO₄ containing sulfide is proposed to be associated with two consecutive reversible one electron processes accompanied by ClO₄^- uptake, sulfide accumulation, and formation of a methylene blue derivative.

Original language	English
Pages (from-to)	1823-1824
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/a905278j
Publication status	Published - 21 Sep 1999

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Marken, F., Blythe, A., Compton, R. G., Bull, S. D., & Davies, S. G. (1999). Sulfide accumulation and sensing based on electrochemical processes in microdroplets of N'-[4-(dihexylamino)phenyl]-N¹,N⁴,N⁴-trihexyl- 1,4-phenylenediamine. Chemical Communications, (18), 1823-1824. https://doi.org/10.1039/a905278j

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AU - Davies, Stephen G.

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10.1039/a905278j

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