Sulfide accumulation and sensing based on electrochemical processes in microdroplets of N'-[4-(dihexylamino)phenyl]-N1,N4,N4-trihexyl- 1,4-phenylenediamine

Frank Marken; Alastair Blythe; Richard G. Compton; Steven D. Bull; Stephen G. Davies

doi:10.1039/a905278j

Sulfide accumulation and sensing based on electrochemical processes in microdroplets of N'-[4-(dihexylamino)phenyl]-N¹,N⁴,N⁴-trihexyl- 1,4-phenylenediamine

Frank Marken, Alastair Blythe, Richard G. Compton, Steven D. Bull, Stephen G. Davies

Research output: Contribution to journal › Article

25 Citations (Scopus)

Abstract

Electroanalytical sulfide detection via oxidation of N¹-[4-(dihexylamino)phenyl]-N¹,N⁴,N⁴-trihexyl-1,4-phenylene diamine (DPTPD) deposited in form of microdroplets onto basal plane pyrolytic graphite electrodes immersed in aqueous 0.1 M NaClO₄ containing sulfide is proposed to be associated with two consecutive reversible one electron processes accompanied by ClO₄^- uptake, sulfide accumulation, and formation of a methylene blue derivative.

Original language	English
Pages (from-to)	1823-1824
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/a905278j
Publication status	Published - 21 Sep 1999

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/a905278j

Link to publication in Scopus

Fingerprint Dive into the research topics of 'Sulfide accumulation and sensing based on electrochemical processes in microdroplets of N'-[4-(dihexylamino)phenyl]-N1,N4,N4-trihexyl- 1,4-phenylenediamine'. Together they form a unique fingerprint.

Cite this

@article{ced0c49c8f80403bb7c92e852df20ece,

title = "Sulfide accumulation and sensing based on electrochemical processes in microdroplets of N'-[4-(dihexylamino)phenyl]-N1,N4,N4-trihexyl- 1,4-phenylenediamine",

abstract = "Electroanalytical sulfide detection via oxidation of N1-[4-(dihexylamino)phenyl]-N1,N4,N4-trihexyl-1,4-phenylene diamine (DPTPD) deposited in form of microdroplets onto basal plane pyrolytic graphite electrodes immersed in aqueous 0.1 M NaClO4 containing sulfide is proposed to be associated with two consecutive reversible one electron processes accompanied by ClO4- uptake, sulfide accumulation, and formation of a methylene blue derivative.",

author = "Frank Marken and Alastair Blythe and Compton, {Richard G.} and Bull, {Steven D.} and Davies, {Stephen G.}",

year = "1999",

month = sep,

day = "21",

doi = "10.1039/a905278j",

language = "English",

pages = "1823--1824",

journal = "Chemical communications (Cambridge, England)",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "18",

}

TY - JOUR

T1 - Sulfide accumulation and sensing based on electrochemical processes in microdroplets of N'-[4-(dihexylamino)phenyl]-N1,N4,N4-trihexyl- 1,4-phenylenediamine

AU - Marken, Frank

AU - Blythe, Alastair

AU - Compton, Richard G.

AU - Bull, Steven D.

AU - Davies, Stephen G.

PY - 1999/9/21

Y1 - 1999/9/21

N2 - Electroanalytical sulfide detection via oxidation of N1-[4-(dihexylamino)phenyl]-N1,N4,N4-trihexyl-1,4-phenylene diamine (DPTPD) deposited in form of microdroplets onto basal plane pyrolytic graphite electrodes immersed in aqueous 0.1 M NaClO4 containing sulfide is proposed to be associated with two consecutive reversible one electron processes accompanied by ClO4- uptake, sulfide accumulation, and formation of a methylene blue derivative.

AB - Electroanalytical sulfide detection via oxidation of N1-[4-(dihexylamino)phenyl]-N1,N4,N4-trihexyl-1,4-phenylene diamine (DPTPD) deposited in form of microdroplets onto basal plane pyrolytic graphite electrodes immersed in aqueous 0.1 M NaClO4 containing sulfide is proposed to be associated with two consecutive reversible one electron processes accompanied by ClO4- uptake, sulfide accumulation, and formation of a methylene blue derivative.

UR - http://www.scopus.com/inward/record.url?scp=0033592431&partnerID=8YFLogxK

U2 - 10.1039/a905278j

DO - 10.1039/a905278j

M3 - Article

AN - SCOPUS:0033592431

SP - 1823

EP - 1824

JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

SN - 1359-7345

IS - 18

ER -