Sulfide accumulation and sensing based on electrochemical processes in microdroplets of N'-[4-(dihexylamino)phenyl]-N1,N4,N4-trihexyl- 1,4-phenylenediamine

Frank Marken, Alastair Blythe, Richard G. Compton, Steven D. Bull, Stephen G. Davies

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Electroanalytical sulfide detection via oxidation of N1-[4-(dihexylamino)phenyl]-N1,N4,N4-trihexyl-1,4-phenylene diamine (DPTPD) deposited in form of microdroplets onto basal plane pyrolytic graphite electrodes immersed in aqueous 0.1 M NaClO4 containing sulfide is proposed to be associated with two consecutive reversible one electron processes accompanied by ClO4- uptake, sulfide accumulation, and formation of a methylene blue derivative.

Original languageEnglish
Pages (from-to)1823-1824
Number of pages2
JournalChemical Communications
Issue number18
DOIs
Publication statusPublished - 21 Sep 1999

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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