Studies towards the synthesis of Pd(II)-containing [2] and [3]catenanes in aqueous media

E. M. López-Vidal; A. Prokofjevs; I. C. Gibbs-Hall; E. J. Dale; J. M. Quintela; C. Peinador

doi:10.1039/c7dt04792d

Studies towards the synthesis of Pd(II)-containing [2] and [3]catenanes in aqueous media

E. M. López-Vidal, A. Prokofjevs, I. C. Gibbs-Hall, E. J. Dale, J. M. Quintela, C. Peinador

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (SciVal)

Abstract

Here is reported the investigation of a synthetic route for the preparation of Pd(ii)-containing catenanes in aqueous media. A pseudorotaxane intermediate was prepared, which can potentially be converted into a series of catenanes. From the pseudorotaxane, using a Pd(ii)-driven clipping step a dinuclear [3]catenane was obtained in the solid state.

Original language	English
Pages (from-to)	2492-2496
Number of pages	5
Journal	Dalton Transactions
Volume	47
Issue number	8
DOIs	https://doi.org/10.1039/c7dt04792d
Publication status	Published - 28 Feb 2018

Funding

This research was supported by the Ministerio de Economía, Industria y Competitividad (Ministerio de Economía y Competitividad FEDER, Grant CTQ2016-75629-P). We are enormously grateful to Prof. Sir James Fraser Stoddart (2016 Nobel Laureate in Chemistry) for supervising and hosting part of this research in his laboratory at Northwestern University. We also thank Ms Charlotte Stern (Northwestern University) for the refinement of the crystal structures reported in this work. E. M. L.-V. thanks the Ministerio de Economía, Industria y Competitividad (FPI program).

ASJC Scopus subject areas

Inorganic Chemistry

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AU - Dale, E. J.

AU - Quintela, J. M.

AU - Peinador, C.

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Studies towards the synthesis of Pd(II)-containing [2] and [3]catenanes in aqueous media

Abstract

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