Structured assembly of heterometallic arrays

Michael A. Beswick; Maxwell K. Davies; Christopher N. Harmer; Alexander D. Hopkins; Marta E.G. Mosquera; Julie S. Palmer; Michael A. Paver; Paul R. Raithby; Dominic S. Wright

doi:10.1080/10426509708545615

Structured assembly of heterometallic arrays

Michael A. Beswick, Maxwell K. Davies, Christopher N. Harmer, Alexander D. Hopkins, Marta E.G. Mosquera, Julie S. Palmer, Michael A. Paver, Paul R. Raithby, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

2 Citations (SciVal)

Abstract

A range of heterometallic cage complexes can be prepared by step-wise metallation reactions of monolithiated primary amines and phosphines ([REHLi]_n; E= N, P) with various Group 13, 14 and 15 metal reagents. The p block imido and phosphinidine anions present in these species are novel ligand systems to main group and transition metals. This simple synthetic approach thereby provides a basis for structured assembly of a range of heterometallic cage and ring compounds.

Original language	English
Pages (from-to)	103-112
Number of pages	10
Journal	Phosphorus, Sulfur and Silicon and Related Elements
Volume	124
DOIs	https://doi.org/10.1080/10426509708545615
Publication status	Published - 1 Jan 1997

Bibliographical note

Funding Information:
Acknowledgements We gratefully the EPSRC (M.A.B., M.K.D., C.N.H., A.D.H., J.S.P.). the Leverhulme Trust (D.S.W.), the Royal Society (P.R.R., D.S.W.), Spanish Government (M.E.G.M.), Jesus College (fellowship for M.A.P.). Electron Tubes, Ruislip, U.K. (Case studentship for A.D.H.).

Funding

Acknowledgements We gratefully the EPSRC (M.A.B., M.K.D., C.N.H., A.D.H., J.S.P.). the Leverhulme Trust (D.S.W.), the Royal Society (P.R.R., D.S.W.), Spanish Government (M.E.G.M.), Jesus College (fellowship for M.A.P.). Electron Tubes, Ruislip, U.K. (Case studentship for A.D.H.).

Keywords

Cages
Heterometallic
Ligands
Main group
Metallation
Rings

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Inorganic Chemistry

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10.1080/10426509708545615

Cite this

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title = "Structured assembly of heterometallic arrays",

abstract = "A range of heterometallic cage complexes can be prepared by step-wise metallation reactions of monolithiated primary amines and phosphines ([REHLi]n; E= N, P) with various Group 13, 14 and 15 metal reagents. The p block imido and phosphinidine anions present in these species are novel ligand systems to main group and transition metals. This simple synthetic approach thereby provides a basis for structured assembly of a range of heterometallic cage and ring compounds.",

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author = "Beswick, {Michael A.} and Davies, {Maxwell K.} and Harmer, {Christopher N.} and Hopkins, {Alexander D.} and Mosquera, {Marta E.G.} and Palmer, {Julie S.} and Paver, {Michael A.} and Raithby, {Paul R.} and Wright, {Dominic S.}",

note = "Funding Information: Acknowledgements We gratefully the EPSRC (M.A.B., M.K.D., C.N.H., A.D.H., J.S.P.). the Leverhulme Trust (D.S.W.), the Royal Society (P.R.R., D.S.W.), Spanish Government (M.E.G.M.), Jesus College (fellowship for M.A.P.). Electron Tubes, Ruislip, U.K. (Case studentship for A.D.H.).",

year = "1997",

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doi = "10.1080/10426509708545615",

language = "English",

volume = "124",

pages = "103--112",

journal = "Phosphorus, Sulfur and Silicon and Related Elements",

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T1 - Structured assembly of heterometallic arrays

AU - Beswick, Michael A.

AU - Davies, Maxwell K.

AU - Harmer, Christopher N.

AU - Hopkins, Alexander D.

AU - Mosquera, Marta E.G.

AU - Palmer, Julie S.

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Wright, Dominic S.

N1 - Funding Information: Acknowledgements We gratefully the EPSRC (M.A.B., M.K.D., C.N.H., A.D.H., J.S.P.). the Leverhulme Trust (D.S.W.), the Royal Society (P.R.R., D.S.W.), Spanish Government (M.E.G.M.), Jesus College (fellowship for M.A.P.). Electron Tubes, Ruislip, U.K. (Case studentship for A.D.H.).

PY - 1997/1/1

Y1 - 1997/1/1

N2 - A range of heterometallic cage complexes can be prepared by step-wise metallation reactions of monolithiated primary amines and phosphines ([REHLi]n; E= N, P) with various Group 13, 14 and 15 metal reagents. The p block imido and phosphinidine anions present in these species are novel ligand systems to main group and transition metals. This simple synthetic approach thereby provides a basis for structured assembly of a range of heterometallic cage and ring compounds.

AB - A range of heterometallic cage complexes can be prepared by step-wise metallation reactions of monolithiated primary amines and phosphines ([REHLi]n; E= N, P) with various Group 13, 14 and 15 metal reagents. The p block imido and phosphinidine anions present in these species are novel ligand systems to main group and transition metals. This simple synthetic approach thereby provides a basis for structured assembly of a range of heterometallic cage and ring compounds.

KW - Cages

KW - Heterometallic

KW - Ligands

KW - Main group

KW - Metallation

KW - Rings

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DO - 10.1080/10426509708545615

M3 - Article

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SN - 1042-6507

VL - 124

SP - 103

EP - 112

JO - Phosphorus, Sulfur and Silicon and Related Elements

JF - Phosphorus, Sulfur and Silicon and Related Elements

ER -

Structured assembly of heterometallic arrays

Abstract

Bibliographical note

Funding

Keywords

ASJC Scopus subject areas

Access to Document

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