Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex

Sarah L Chatwin; Richard A Diggle; Rodolphe F R Jazzar; Stuart A MacGregor; Mary F Mahon; Michael K Whittlesey

doi:10.1021/ic030241i

Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex

Sarah L Chatwin
, Richard A Diggle
, Rodolphe F R Jazzar
, Stuart A MacGregor
, Mary F Mahon
, Michael K Whittlesey

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

39 Citations (SciVal)

Abstract

Addition of 1 atm of H2S to [Ru(IMeS)(2)(CO)(EtOH)H-2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMeS)(2)(CO)(H2S)H-2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMeS)(2)(CO)(SH)(2)] 3. Preliminary studies show that 3 reacts with both H-2 and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized.

Original language	English
Pages (from-to)	7695-7697
Number of pages	3
Journal	Inorganic Chemistry
Volume	42
Issue number	24
DOIs	https://doi.org/10.1021/ic030241i
Publication status	Published - 2003

Keywords

hydrosulfido ruthenium imidazolylidene thiol complex prepn crystal mol structure
Molecular mechanics (prepn.
reactivity
structure
and computational studies of ruthenium hydrogen sulfide dihydride complex)
prepn.
Density functional theory
Molecular structure (of imidazolylidene ruthenium hydrogen sulfide dihydride and bis-hydrosulfido complexes)
Crystal structure
Molecular structure (optimized
imidazolylidene ruthenium hydrogen sulfide dihydride complex prepn crystal structure

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10.1021/ic030241i

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@article{868c76c7575f45c9a440a1faffe8ed87,

title = "Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex",

abstract = "Addition of 1 atm of H2S to [Ru(IMeS)(2)(CO)(EtOH)H-2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMeS)(2)(CO)(H2S)H-2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMeS)(2)(CO)(SH)(2)] 3. Preliminary studies show that 3 reacts with both H-2 and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized.",

keywords = "hydrosulfido ruthenium imidazolylidene thiol complex prepn crystal mol structure, Molecular mechanics (prepn., reactivity, structure, and computational studies of ruthenium hydrogen sulfide dihydride complex), prepn., Density functional theory, Molecular structure (of imidazolylidene ruthenium hydrogen sulfide dihydride and bis-hydrosulfido complexes), Crystal structure, Molecular structure (optimized, imidazolylidene ruthenium hydrogen sulfide dihydride complex prepn crystal structure",

author = "Chatwin, \{Sarah L\} and Diggle, \{Richard A\} and Jazzar, \{Rodolphe F R\} and MacGregor, \{Stuart A\} and Mahon, \{Mary F\} and Whittlesey, \{Michael K\}",

year = "2003",

doi = "10.1021/ic030241i",

language = "English",

volume = "42",

pages = "7695--7697",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "24",

}

TY - JOUR

T1 - Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex

AU - Chatwin, Sarah L

AU - Diggle, Richard A

AU - Jazzar, Rodolphe F R

AU - MacGregor, Stuart A

AU - Mahon, Mary F

AU - Whittlesey, Michael K

PY - 2003

Y1 - 2003

N2 - Addition of 1 atm of H2S to [Ru(IMeS)(2)(CO)(EtOH)H-2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMeS)(2)(CO)(H2S)H-2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMeS)(2)(CO)(SH)(2)] 3. Preliminary studies show that 3 reacts with both H-2 and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized.

AB - Addition of 1 atm of H2S to [Ru(IMeS)(2)(CO)(EtOH)H-2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMeS)(2)(CO)(H2S)H-2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMeS)(2)(CO)(SH)(2)] 3. Preliminary studies show that 3 reacts with both H-2 and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized.

KW - hydrosulfido ruthenium imidazolylidene thiol complex prepn crystal mol structure

KW - Molecular mechanics (prepn.

KW - reactivity

KW - structure

KW - and computational studies of ruthenium hydrogen sulfide dihydride complex)

KW - prepn.

KW - Density functional theory

KW - Molecular structure (of imidazolylidene ruthenium hydrogen sulfide dihydride and bis-hydrosulfido complexes)

KW - Crystal structure

KW - Molecular structure (optimized

KW - imidazolylidene ruthenium hydrogen sulfide dihydride complex prepn crystal structure

UR - http://dx.doi.org/10.1021/ic030241i

U2 - 10.1021/ic030241i

DO - 10.1021/ic030241i

M3 - Article

SN - 0020-1669

VL - 42

SP - 7695

EP - 7697

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 24

ER -

Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex

Abstract

Keywords

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