Structure of 2-methyl-3-phenyl-3-[(tri-p-tolyl)germyl] propanoic acid, (p-CH3C6H4)(3)GeCH(Ph)CH(Me)CO2H. CHCl3

Din Imtiaz ud, M Mazhar, S Ali, S Dastgir, K C Molloy, M F Mahon

Research output: Contribution to journalArticle

Abstract

In the title compound, one molecule of CHCl3, is also present in each asymmetric unit. The germanium adopts a distorted tetrahedral coordination geometry [C-Ge-C: 106.5(1) - 111.7(1)degrees]. experimental error [1.951(3) - 1.955(3) Angstrom], however Ge-C(22) of the substituted propanoic acid is significantly longer [1.997(3) Angstrom]. The molecule dimerises through hydrogen bonds between carboxylic acid groups, in a conventional Manner. The hydrogen bor.d is relatively strong [O(1)...O(2'): 2.661(2); H(2A)-O(1'): 1.81(4) Angstrom;
Original languageEnglish
Pages (from-to)315-+
JournalMain Group Metal Chemistry
Volume25
Issue number5
Publication statusPublished - 2002

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Molecules
Acids
Carboxylic acids
Germanium
Hydrogen bonds
Hydrogen
Geometry

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Structure of 2-methyl-3-phenyl-3-[(tri-p-tolyl)germyl] propanoic acid, (p-CH3C6H4)(3)GeCH(Ph)CH(Me)CO2H. CHCl3. / Imtiaz ud, Din; Mazhar, M; Ali, S; Dastgir, S; Molloy, K C; Mahon, M F.

In: Main Group Metal Chemistry, Vol. 25, No. 5, 2002, p. 315-+.

Research output: Contribution to journalArticle

Imtiaz ud, Din ; Mazhar, M ; Ali, S ; Dastgir, S ; Molloy, K C ; Mahon, M F. / Structure of 2-methyl-3-phenyl-3-[(tri-p-tolyl)germyl] propanoic acid, (p-CH3C6H4)(3)GeCH(Ph)CH(Me)CO2H. CHCl3. In: Main Group Metal Chemistry. 2002 ; Vol. 25, No. 5. pp. 315-+.
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abstract = "In the title compound, one molecule of CHCl3, is also present in each asymmetric unit. The germanium adopts a distorted tetrahedral coordination geometry [C-Ge-C: 106.5(1) - 111.7(1)degrees]. experimental error [1.951(3) - 1.955(3) Angstrom], however Ge-C(22) of the substituted propanoic acid is significantly longer [1.997(3) Angstrom]. The molecule dimerises through hydrogen bonds between carboxylic acid groups, in a conventional Manner. The hydrogen bor.d is relatively strong [O(1)...O(2'): 2.661(2); H(2A)-O(1'): 1.81(4) Angstrom;",
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T1 - Structure of 2-methyl-3-phenyl-3-[(tri-p-tolyl)germyl] propanoic acid, (p-CH3C6H4)(3)GeCH(Ph)CH(Me)CO2H. CHCl3

AU - Imtiaz ud, Din

AU - Mazhar, M

AU - Ali, S

AU - Dastgir, S

AU - Molloy, K C

AU - Mahon, M F

N1 - ID number: ISI:000176468200012

PY - 2002

Y1 - 2002

N2 - In the title compound, one molecule of CHCl3, is also present in each asymmetric unit. The germanium adopts a distorted tetrahedral coordination geometry [C-Ge-C: 106.5(1) - 111.7(1)degrees]. experimental error [1.951(3) - 1.955(3) Angstrom], however Ge-C(22) of the substituted propanoic acid is significantly longer [1.997(3) Angstrom]. The molecule dimerises through hydrogen bonds between carboxylic acid groups, in a conventional Manner. The hydrogen bor.d is relatively strong [O(1)...O(2'): 2.661(2); H(2A)-O(1'): 1.81(4) Angstrom;

AB - In the title compound, one molecule of CHCl3, is also present in each asymmetric unit. The germanium adopts a distorted tetrahedral coordination geometry [C-Ge-C: 106.5(1) - 111.7(1)degrees]. experimental error [1.951(3) - 1.955(3) Angstrom], however Ge-C(22) of the substituted propanoic acid is significantly longer [1.997(3) Angstrom]. The molecule dimerises through hydrogen bonds between carboxylic acid groups, in a conventional Manner. The hydrogen bor.d is relatively strong [O(1)...O(2'): 2.661(2); H(2A)-O(1'): 1.81(4) Angstrom;

M3 - Article

VL - 25

SP - 315-+

JO - Main Group Metal Chemistry

JF - Main Group Metal Chemistry

SN - 0792-1241

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