Structure of β-SrRh2O4 from X-ray and neutron powder diffraction

A. L. Hector, W. Levason, M. T. Weller

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

β-SrRhO, a novel high temperature phase, is prepared as black powder by solid state reaction of SrCO with Rh in air. The compound crystallises in the space group P63c, Z = 1, with a = 3.0626(2) Å and c = 11.3996(7) Å. The structure consists of CdI-type layers of edge sharing RhO octahedra with an AABB oxygen layer sequence. Strontium is found in partial occupation of both available interlayer sites, in trigonal prismatic coordination.
Original languageEnglish
Pages (from-to)679-687
Number of pages9
JournalEuropean Journal of Solid State and Inorganic Chemistry
Volume35
Issue number10-11
DOIs
Publication statusPublished - 1998

Fingerprint

Strontium
Neutron powder diffraction
Solid state reactions
Powders
X ray powder diffraction
Oxygen
Air
Temperature

Cite this

Structure of β-SrRh2O4 from X-ray and neutron powder diffraction. / Hector, A. L.; Levason, W.; Weller, M. T.

In: European Journal of Solid State and Inorganic Chemistry, Vol. 35, No. 10-11, 1998, p. 679-687.

Research output: Contribution to journalArticle

Hector, A. L. ; Levason, W. ; Weller, M. T. / Structure of β-SrRh2O4 from X-ray and neutron powder diffraction. In: European Journal of Solid State and Inorganic Chemistry. 1998 ; Vol. 35, No. 10-11. pp. 679-687.
@article{0fb259731d8d49bd93bb69a9e959d2ef,
title = "Structure of β-SrRh2O4 from X-ray and neutron powder diffraction",
abstract = "β-SrRhO, a novel high temperature phase, is prepared as black powder by solid state reaction of SrCO with Rh in air. The compound crystallises in the space group P63c, Z = 1, with a = 3.0626(2) {\AA} and c = 11.3996(7) {\AA}. The structure consists of CdI-type layers of edge sharing RhO octahedra with an AABB oxygen layer sequence. Strontium is found in partial occupation of both available interlayer sites, in trigonal prismatic coordination.",
author = "Hector, {A. L.} and W. Levason and Weller, {M. T.}",
note = "Copyright 2007 Elsevier B.V., All rights reserved.",
year = "1998",
doi = "10.1016/S0992-4361(99)80008-3",
language = "English",
volume = "35",
pages = "679--687",
journal = "European Journal of Solid State and Inorganic Chemistry",
issn = "0992-4361",
publisher = "Gauthier Villars Editeur",
number = "10-11",

}

TY - JOUR

T1 - Structure of β-SrRh2O4 from X-ray and neutron powder diffraction

AU - Hector, A. L.

AU - Levason, W.

AU - Weller, M. T.

N1 - Copyright 2007 Elsevier B.V., All rights reserved.

PY - 1998

Y1 - 1998

N2 - β-SrRhO, a novel high temperature phase, is prepared as black powder by solid state reaction of SrCO with Rh in air. The compound crystallises in the space group P63c, Z = 1, with a = 3.0626(2) Å and c = 11.3996(7) Å. The structure consists of CdI-type layers of edge sharing RhO octahedra with an AABB oxygen layer sequence. Strontium is found in partial occupation of both available interlayer sites, in trigonal prismatic coordination.

AB - β-SrRhO, a novel high temperature phase, is prepared as black powder by solid state reaction of SrCO with Rh in air. The compound crystallises in the space group P63c, Z = 1, with a = 3.0626(2) Å and c = 11.3996(7) Å. The structure consists of CdI-type layers of edge sharing RhO octahedra with an AABB oxygen layer sequence. Strontium is found in partial occupation of both available interlayer sites, in trigonal prismatic coordination.

UR - http://www.scopus.com/inward/record.url?scp=0000571842&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1016/S0992-4361(99)80008-3

U2 - 10.1016/S0992-4361(99)80008-3

DO - 10.1016/S0992-4361(99)80008-3

M3 - Article

VL - 35

SP - 679

EP - 687

JO - European Journal of Solid State and Inorganic Chemistry

JF - European Journal of Solid State and Inorganic Chemistry

SN - 0992-4361

IS - 10-11

ER -