Structure and reactivity of [{Te(NMe2)2}∞]; application to the preparation of metalloorganic tellurium(II) compounds

Robert E. Allan; Heinz Gornitzka; Jörg Kärcher; Michael A. Paver; Moira Ann Rennie; Christopher A. Russell; Paul R. Raithby; Dietmar Stalke; Alexander Steiner; Dominic S. Wright

doi:10.1039/DT9960001727

Structure and reactivity of [{Te(NMe₂)₂}_∞]; application to the preparation of metalloorganic tellurium(II) compounds

Robert E. Allan
, Heinz Gornitzka
, Jörg Kärcher
, Michael A. Paver
, Moira Ann Rennie
, Christopher A. Russell
, Paul R. Raithby
, Dietmar Stalke
, Alexander Steiner
, Dominic S. Wright

University of Cambridge
Universtät der Göttingen

Research output: Contribution to journal › Article › peer-review

32 Citations (SciVal)

Abstract

Condensation of the highly reactive complex [{Te(NMe₂)₂}_∞] 1, prepared by the reaction of TeCl₄ and Li[NMe₂] (1:4 equivalents), with various organic acids has been used as a route to tellurium(II) metalloorganic complexes. The crystal structures of 1 and of Te(SCPh₃)₂ 2, formed by the reaction of 1 with Ph₃CSH (1:2 equivalents), have been determined.

Original language	English
Pages (from-to)	1727-1730
Number of pages	4
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	8
DOIs	https://doi.org/10.1039/DT9960001727
Publication status	Published - 1 Jan 1996

ASJC Scopus subject areas

General Chemistry

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10.1039/DT9960001727

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Allan, R. E., Gornitzka, H., Kärcher, J., Paver, M. A., Rennie, M. A., Russell, C. A., Raithby, P. R., Stalke, D., Steiner, A., & Wright, D. S. (1996). Structure and reactivity of [{Te(NMe₂)₂}_∞]; application to the preparation of metalloorganic tellurium(II) compounds. Journal of the Chemical Society - Dalton Transactions, (8), 1727-1730. https://doi.org/10.1039/DT9960001727

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title = "Structure and reactivity of [\{Te(NMe2)2\}∞]; application to the preparation of metalloorganic tellurium(II) compounds",

abstract = "Condensation of the highly reactive complex [\{Te(NMe2)2\}∞] 1, prepared by the reaction of TeCl4 and Li[NMe2] (1:4 equivalents), with various organic acids has been used as a route to tellurium(II) metalloorganic complexes. The crystal structures of 1 and of Te(SCPh3)2 2, formed by the reaction of 1 with Ph3CSH (1:2 equivalents), have been determined.",

author = "Allan, \{Robert E.\} and Heinz Gornitzka and J{\"o}rg K{\"a}rcher and Paver, \{Michael A.\} and Rennie, \{Moira Ann\} and Russell, \{Christopher A.\} and Raithby, \{Paul R.\} and Dietmar Stalke and Alexander Steiner and Wright, \{Dominic S.\}",

year = "1996",

month = jan,

day = "1",

doi = "10.1039/DT9960001727",

language = "English",

pages = "1727--1730",

journal = "Journal of the Chemical Society - Dalton Transactions",

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T1 - Structure and reactivity of [{Te(NMe2)2}∞]; application to the preparation of metalloorganic tellurium(II) compounds

AU - Allan, Robert E.

AU - Gornitzka, Heinz

AU - Kärcher, Jörg

AU - Paver, Michael A.

AU - Rennie, Moira Ann

AU - Russell, Christopher A.

AU - Raithby, Paul R.

AU - Stalke, Dietmar

AU - Steiner, Alexander

AU - Wright, Dominic S.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Condensation of the highly reactive complex [{Te(NMe2)2}∞] 1, prepared by the reaction of TeCl4 and Li[NMe2] (1:4 equivalents), with various organic acids has been used as a route to tellurium(II) metalloorganic complexes. The crystal structures of 1 and of Te(SCPh3)2 2, formed by the reaction of 1 with Ph3CSH (1:2 equivalents), have been determined.

AB - Condensation of the highly reactive complex [{Te(NMe2)2}∞] 1, prepared by the reaction of TeCl4 and Li[NMe2] (1:4 equivalents), with various organic acids has been used as a route to tellurium(II) metalloorganic complexes. The crystal structures of 1 and of Te(SCPh3)2 2, formed by the reaction of 1 with Ph3CSH (1:2 equivalents), have been determined.

UR - https://www.scopus.com/pages/publications/33751353569

U2 - 10.1039/DT9960001727

DO - 10.1039/DT9960001727

M3 - Article

AN - SCOPUS:33751353569

SN - 0300-9246

SP - 1727

EP - 1730

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 8

ER -

Structure and reactivity of [{Te(NMe₂)₂}_∞]; application to the preparation of metalloorganic tellurium(II) compounds

Abstract

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