Structure and reactivity of [{Te(NMe2)2}]; application to the preparation of metalloorganic tellurium(II) compounds

Robert E. Allan, Heinz Gornitzka, Jörg Kärcher, Michael A. Paver, Moira Ann Rennie, Christopher A. Russell, Paul R. Raithby, Dietmar Stalke, Alexander Steiner, Dominic S. Wright

Research output: Contribution to journalArticlepeer-review

Abstract

Condensation of the highly reactive complex [{Te(NMe2)2}] 1, prepared by the reaction of TeCl4 and Li[NMe2] (1:4 equivalents), with various organic acids has been used as a route to tellurium(II) metalloorganic complexes. The crystal structures of 1 and of Te(SCPh3)2 2, formed by the reaction of 1 with Ph3CSH (1:2 equivalents), have been determined.

Original languageEnglish
Pages (from-to)1727-1730
Number of pages4
JournalJournal of the Chemical Society - Dalton Transactions
Issue number8
DOIs
Publication statusPublished - 1 Jan 1996

ASJC Scopus subject areas

  • Chemistry(all)

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