TY - JOUR
T1 - Structure and reactivity of a dimetallic rhenium hydride complex with a rhenium-rhenium double bond
T2 - X-ray crystal structures of [Re2(CO) 6(Ph2PCH2PPh2)H2] and [Re2(CO)6(Ph2PCH2PPh 2)-(NCHMe)H]
AU - Mays, Martin J.
AU - Prest, David W.
AU - Raithby, Paul R.
PY - 1980
Y1 - 1980
N2 - The complex [Re2(CO)6(Ph2PCH 2PPh2)H2] with an Re-Re double bond has been prepared and its crystal structure determined, it reacts with (MeO) 3P, RNC, and MeCN under mild conditions giving 1:1 adducts in which the dimetallic unit is preserved and with MeCN two separable isomers are obtained one of which has been shown by X-ray analysis to be the insertion product [Re2(CO)6(Ph2PCH2PPh 2)(NCHMe)H].
AB - The complex [Re2(CO)6(Ph2PCH 2PPh2)H2] with an Re-Re double bond has been prepared and its crystal structure determined, it reacts with (MeO) 3P, RNC, and MeCN under mild conditions giving 1:1 adducts in which the dimetallic unit is preserved and with MeCN two separable isomers are obtained one of which has been shown by X-ray analysis to be the insertion product [Re2(CO)6(Ph2PCH2PPh 2)(NCHMe)H].
UR - http://www.scopus.com/inward/record.url?scp=37049110222&partnerID=8YFLogxK
U2 - 10.1039/C39800000171
DO - 10.1039/C39800000171
M3 - Article
AN - SCOPUS:37049110222
SN - 0022-4936
SP - 171
EP - 173
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 4
ER -