Structure and properties of SrCu(OH4)·H2O

Maria J. Pack; Wyona Patalinghug; Mark T. Weller

doi:10.1039/DT9960000007

Structure and properties of SrCu(OH₄)·H₂O

Maria J. Pack, Wyona Patalinghug, Mark T. Weller

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of SrCu(OH)·HO has been determined from a single-crystal X-ray refinement and shown to contain isolated square-planar [Cu(OH)] groups separated by strontium ions and hydrogen bonded to water molecules. ESR, IR and UV/VIS spectra are also reported for this compound and are consistent with the presence of discrete [Cu(OH)] square planes. Thermal decomposition of this material proceeded by a complex multistage process via Sr(OH)Cu(OH), through CuO and Sr(OH), to SrCuO and CuO. Consideration of the structure of SrCu(OH)·HO shows that the relative orientation of the [Cu(OH)] units is such that they do not crosslink to form infinite CuO sheets.

Original language	English
Pages (from-to)	7-10
Journal	Journal of the Chemical Society: Dalton Transactions
Volume	1996
Issue number	1
DOIs	https://doi.org/10.1039/DT9960000007
Publication status	Published - 1996

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title = "Structure and properties of SrCu(OH4)·H2O",

abstract = "The structure of SrCu(OH)·HO has been determined from a single-crystal X-ray refinement and shown to contain isolated square-planar [Cu(OH)] groups separated by strontium ions and hydrogen bonded to water molecules. ESR, IR and UV/VIS spectra are also reported for this compound and are consistent with the presence of discrete [Cu(OH)] square planes. Thermal decomposition of this material proceeded by a complex multistage process via Sr(OH)Cu(OH), through CuO and Sr(OH), to SrCuO and CuO. Consideration of the structure of SrCu(OH)·HO shows that the relative orientation of the [Cu(OH)] units is such that they do not crosslink to form infinite CuO sheets.",

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doi = "10.1039/DT9960000007",

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T1 - Structure and properties of SrCu(OH4)·H2O

AU - Pack, Maria J.

AU - Patalinghug, Wyona

AU - Weller, Mark T.

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N2 - The structure of SrCu(OH)·HO has been determined from a single-crystal X-ray refinement and shown to contain isolated square-planar [Cu(OH)] groups separated by strontium ions and hydrogen bonded to water molecules. ESR, IR and UV/VIS spectra are also reported for this compound and are consistent with the presence of discrete [Cu(OH)] square planes. Thermal decomposition of this material proceeded by a complex multistage process via Sr(OH)Cu(OH), through CuO and Sr(OH), to SrCuO and CuO. Consideration of the structure of SrCu(OH)·HO shows that the relative orientation of the [Cu(OH)] units is such that they do not crosslink to form infinite CuO sheets.

AB - The structure of SrCu(OH)·HO has been determined from a single-crystal X-ray refinement and shown to contain isolated square-planar [Cu(OH)] groups separated by strontium ions and hydrogen bonded to water molecules. ESR, IR and UV/VIS spectra are also reported for this compound and are consistent with the presence of discrete [Cu(OH)] square planes. Thermal decomposition of this material proceeded by a complex multistage process via Sr(OH)Cu(OH), through CuO and Sr(OH), to SrCuO and CuO. Consideration of the structure of SrCu(OH)·HO shows that the relative orientation of the [Cu(OH)] units is such that they do not crosslink to form infinite CuO sheets.

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Structure and properties of SrCu(OH₄)·H₂O

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