Structure and bonding in Au2Os mixed-metal carbonyl clusters: the crystal and molecular structure of [Os(CO)4AuPPh32]

Brian F. G. Johnson; Jack Lewis; Paul R. Raithby; Arthur Sanders

doi:10.1016/S0022-328X(00)98687-X

Structure and bonding in Au₂Os mixed-metal carbonyl clusters: the crystal and molecular structure of [Os(CO)₄AuPPh₃₂]

Brian F. G. Johnson, Jack Lewis, Paul R. Raithby, Arthur Sanders

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

An X-ray analysis of [Os(CO)₄AuPPh₃₂] shows that the metal atoms define an isosceles triangle in which the Au-Au distance is 2.929(1) Å, which is ca. 0.1 Å shorter than in the corresponding iron analogue [Fe(CO)₄AuPPh₃₂].

Original language	English
Pages (from-to)	C29-C32
Journal	Journal of Organometallic Chemistry
Volume	260
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)98687-X
Publication status	Published - 3 Jan 1984

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)98687-X

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title = "Structure and bonding in Au2Os mixed-metal carbonyl clusters: the crystal and molecular structure of [Os(CO)4AuPPh32]",

abstract = "An X-ray analysis of [Os(CO)4AuPPh32] shows that the metal atoms define an isosceles triangle in which the Au-Au distance is 2.929(1) {\AA}, which is ca. 0.1 {\AA} shorter than in the corresponding iron analogue [Fe(CO)4AuPPh32].",

author = "Johnson, {Brian F. G.} and Jack Lewis and Raithby, {Paul R.} and Arthur Sanders",

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AU - Raithby, Paul R.

AU - Sanders, Arthur

PY - 1984/1/3

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N2 - An X-ray analysis of [Os(CO)4AuPPh32] shows that the metal atoms define an isosceles triangle in which the Au-Au distance is 2.929(1) Å, which is ca. 0.1 Å shorter than in the corresponding iron analogue [Fe(CO)4AuPPh32].

AB - An X-ray analysis of [Os(CO)4AuPPh32] shows that the metal atoms define an isosceles triangle in which the Au-Au distance is 2.929(1) Å, which is ca. 0.1 Å shorter than in the corresponding iron analogue [Fe(CO)4AuPPh32].

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SP - C29-C32

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IS - 1

ER -

Structure and bonding in Au₂Os mixed-metal carbonyl clusters: the crystal and molecular structure of [Os(CO)₄AuPPh₃₂]

Abstract

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