Structurally tuned lead magnesium titanate perovskite as a photoelectrode material for enhanced photoelectrochemical water splitting

Sundaram Chandrasekaran, Eui Jung Kim, Jin Suk Chung, Ik Keun Yoo, Velusamy Senthilkumar, Yong Soo Kim, Chris R. Bowen, Vaia Adamaki, Seung Hyun Hur

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This is the first demonstration of four distinct types of Lead Magnesium Titanate (PMT) perovskites including spheres, flakes, hierarchical flower and thin microbelt shapes that were finely tuned via facile solution method to develop cost effective and high performance photoanode materials for water splitting. The influence of solvent effects during structural tuning, purity, morphology, optical absorption, structural phase transition and stoichiometric formation of the prepared Lead Magnesium Titanate perovskites has been discussed in detail. A remarkable observation is that the thin microbelts structured PMT perovskite (PMTT) exhibited an excellent water splitting performance and it is more sensitive to the illuminated visible light. Owing to the unique structural features, the photoconversion efficiency value of PMTT perovskite is ∼3.9, 3.54, 2.85 and 1.52 times higher than those of other prepared PMT perovskites including pristine PbTiO3. The excellent water splitting performance of PMTT (thin microbelts) may be ascribed to the remarkable structural features that include a large surface area, high optical absorbance, more active sites and high interface area of the microbelts, which provide large contact areas between the electrolyte and highly active materials for electrolyte diffusion and a rapid route for charge transfer with minimal diffusion resistance. In addition, each thin microbelt is directly in contact with the Ni foam substrate, which can also shorten the diffusion path for the electrons. The demonstrated approach paves the way for low-cost and high-throughput production of next generation, high performance and highly active water splitting perovskite photocatalysts.

Original languageEnglish
Pages (from-to)682-690
Number of pages9
JournalChemical Engineering Journal
Early online date20 Oct 2016
Publication statusPublished - 1 Feb 2017


  • Lead Magnesium Titanate
  • Microbelt
  • PbTiO
  • Perovskites
  • Water splitting


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