Structural transformations on vitrification in the fragile glass-forming system CaAl2O4

James W E Drewitt, Louis Hennet, Anita Zeidler, Sandro Jahn, Philip S Salmon, Daniel R Neuville, Henry E Fischer

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

The structure of the fragile glass-forming material CaAl2O4 was measured by applying the method of neutron diffraction with Ca isotope substitution to the laser-heated aerodynamically levitated liquid at 1973(30) K and to the glass at 300(1) K. The results, interpreted with the aid of molecular dynamics simulations, reveal key structural modifications on multiple length scales. Specifically, there is a reorganization on quenching that leads to an almost complete breakdown of the AlO5 polyhedra and threefold coordinated oxygen atoms present in the liquid, and to their replacement by a predominantly corner-sharing network of AlO4 tetrahedra in the glass. This process is accompanied by the formation of branched chains of edge and face-sharing Ca-centered polyhedra that give cationic ordering on an intermediate length scale, where the measured coordination number for O around Ca is 6.0(2) for the liquid and 6.4(2) for the glass.
LanguageEnglish
Article number235501
Number of pages5
JournalPhysical Review Letters
Volume109
Issue number23
Early online date5 Dec 2012
DOIs
StatusPublished - 7 Dec 2012

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vitrification
glass
polyhedrons
liquids
coordination number
tetrahedrons
neutron diffraction
oxygen atoms
isotopes
breakdown
quenching
substitutes
molecular dynamics
lasers
simulation

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Structural transformations on vitrification in the fragile glass-forming system CaAl2O4. / Drewitt, James W E; Hennet, Louis; Zeidler, Anita; Jahn, Sandro; Salmon, Philip S; Neuville, Daniel R; Fischer, Henry E.

In: Physical Review Letters, Vol. 109, No. 23, 235501, 07.12.2012.

Research output: Contribution to journalArticle

Drewitt, James W E ; Hennet, Louis ; Zeidler, Anita ; Jahn, Sandro ; Salmon, Philip S ; Neuville, Daniel R ; Fischer, Henry E. / Structural transformations on vitrification in the fragile glass-forming system CaAl2O4. In: Physical Review Letters. 2012 ; Vol. 109, No. 23.
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