Structural isomers of H2Ru4C(CO)12; X-ray crystal structure of Ru4C(CO)13

Alan G. Cowie; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby

doi:10.1016/S0022-328X(00)99004-1

Structural isomers of H₂Ru₄C(CO)₁₂; X-ray crystal structure of Ru₄C(CO)₁₃

Alan G. Cowie, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The anionic hydrido cluster [HRu₄C(CO)₁₂]^- and the neutral dihydride H₂Ru₄C(CO)₁₂ have been prepared in good yield. Spectroscopic studies of H₂Ru₄C(CO)₁₂ indicate that two isomers are formed, one with a structure similar to that of H₂Fe₄C(CO)₁₂ the other with metal-bonded hydrido ligands. The parent carbido cluster Ru₄C(CO)₁₃ has been synthesised from the hydrido anion, and has a structure similar to that of the analogous iron cluster Fe₄C(CO)₁₃.

Original language	English
Pages (from-to)	C63-C67
Journal	Journal of Organometallic Chemistry
Volume	306
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)99004-1
Publication status	Published - 3 Jun 1986

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)99004-1

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title = "Structural isomers of H2Ru4C(CO)12; X-ray crystal structure of Ru4C(CO)13",

abstract = "The anionic hydrido cluster [HRu4C(CO)12]- and the neutral dihydride H2Ru4C(CO)12 have been prepared in good yield. Spectroscopic studies of H2Ru4C(CO)12 indicate that two isomers are formed, one with a structure similar to that of H2Fe4C(CO)12 the other with metal-bonded hydrido ligands. The parent carbido cluster Ru4C(CO)13 has been synthesised from the hydrido anion, and has a structure similar to that of the analogous iron cluster Fe4C(CO)13.",

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T1 - Structural isomers of H2Ru4C(CO)12; X-ray crystal structure of Ru4C(CO)13

AU - Cowie, Alan G.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

PY - 1986/6/3

Y1 - 1986/6/3

N2 - The anionic hydrido cluster [HRu4C(CO)12]- and the neutral dihydride H2Ru4C(CO)12 have been prepared in good yield. Spectroscopic studies of H2Ru4C(CO)12 indicate that two isomers are formed, one with a structure similar to that of H2Fe4C(CO)12 the other with metal-bonded hydrido ligands. The parent carbido cluster Ru4C(CO)13 has been synthesised from the hydrido anion, and has a structure similar to that of the analogous iron cluster Fe4C(CO)13.

AB - The anionic hydrido cluster [HRu4C(CO)12]- and the neutral dihydride H2Ru4C(CO)12 have been prepared in good yield. Spectroscopic studies of H2Ru4C(CO)12 indicate that two isomers are formed, one with a structure similar to that of H2Fe4C(CO)12 the other with metal-bonded hydrido ligands. The parent carbido cluster Ru4C(CO)13 has been synthesised from the hydrido anion, and has a structure similar to that of the analogous iron cluster Fe4C(CO)13.

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IS - 3

ER -

Structural isomers of H₂Ru₄C(CO)₁₂; X-ray crystal structure of Ru₄C(CO)₁₃

Abstract

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