Structural diversity in organolithium, -sodium, and -potassium cyanocuprates

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29 Citations (Scopus)

Abstract

An unprecedented series of 'lower order' alkali metal (Li, Na, K) cyanocuprates containing the bulky (Me2PhSi)3C ligand has been synthesized. Both monomeric and dimeric forms of the lithium derivative have been characterized; the tetrameric potassium compound provides a striking example of molecular self-assembly driven by K-π-aryl interactions.

Original languageEnglish
Pages (from-to)5780-5783
Number of pages4
JournalOrganometallics
Volume19
Issue number26
DOIs
Publication statusPublished - 1 Dec 2000

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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