Structural diversity in organolithium, -sodium, and -potassium cyanocuprates

Michael S. Hill

doi:10.1021/om000748q

Structural diversity in organolithium, -sodium, and -potassium cyanocuprates

Michael S. Hill

University of Sussex

Research output: Contribution to journal › Article › peer-review

28 Citations (SciVal)

Abstract

An unprecedented series of 'lower order' alkali metal (Li, Na, K) cyanocuprates containing the bulky (Me₂PhSi)₃C ligand has been synthesized. Both monomeric and dimeric forms of the lithium derivative have been characterized; the tetrameric potassium compound provides a striking example of molecular self-assembly driven by K-π-aryl interactions.

Original language	English
Pages (from-to)	5780-5783
Number of pages	4
Journal	Organometallics
Volume	19
Issue number	26
DOIs	https://doi.org/10.1021/om000748q
Publication status	Published - 1 Dec 2000

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om000748q

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abstract = "An unprecedented series of 'lower order' alkali metal (Li, Na, K) cyanocuprates containing the bulky (Me2PhSi)3C ligand has been synthesized. Both monomeric and dimeric forms of the lithium derivative have been characterized; the tetrameric potassium compound provides a striking example of molecular self-assembly driven by K-π-aryl interactions.",

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AB - An unprecedented series of 'lower order' alkali metal (Li, Na, K) cyanocuprates containing the bulky (Me2PhSi)3C ligand has been synthesized. Both monomeric and dimeric forms of the lithium derivative have been characterized; the tetrameric potassium compound provides a striking example of molecular self-assembly driven by K-π-aryl interactions.

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Structural diversity in organolithium, -sodium, and -potassium cyanocuprates

Abstract

ASJC Scopus subject areas

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