Structural characterisation of a water intercalated bis-ainide tecton and copper promoted monohydration of a dinitrile

J K Bjernemose; C J McKenzie; P R Raithby; S J Teat

doi:10.1039/b306169h

Structural characterisation of a water intercalated bis-ainide tecton and copper promoted monohydration of a dinitrile

J K Bjernemose, C J McKenzie, P R Raithby, S J Teat

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (SciVal)

Abstract

Chains of H-bonded water intercalated bis-amide pairs were found in the structure of {[Cu(cdc)(2)(OH2)].H2O}(infinity). (1) (cdc(-) = carbamoyldicyanomethanide); specific hydration of one nitrile group of the cdc(-) ligands of 1 to give the previously unknown anion cyanomalonamidate (cyma(-)) as a ligand in [Cu(cyma)(2)].H2O is possible.

Original language	English
Pages (from-to)	2639-2640
Number of pages	2
Journal	Dalton Transactions
Issue number	13
DOIs	https://doi.org/10.1039/b306169h
Publication status	Published - 2003

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ID number: ISI:000184157800003

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title = "Structural characterisation of a water intercalated bis-ainide tecton and copper promoted monohydration of a dinitrile",

abstract = "Chains of H-bonded water intercalated bis-amide pairs were found in the structure of \{[Cu(cdc)(2)(OH2)].H2O\}(infinity). (1) (cdc(-) = carbamoyldicyanomethanide); specific hydration of one nitrile group of the cdc(-) ligands of 1 to give the previously unknown anion cyanomalonamidate (cyma(-)) as a ligand in [Cu(cyma)(2)].H2O is possible.",

author = "Bjernemose, \{J K\} and McKenzie, \{C J\} and Raithby, \{P R\} and Teat, \{S J\}",

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doi = "10.1039/b306169h",

language = "English",

pages = "2639--2640",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Structural characterisation of a water intercalated bis-ainide tecton and copper promoted monohydration of a dinitrile

AU - Bjernemose, J K

AU - McKenzie, C J

AU - Raithby, P R

AU - Teat, S J

N1 - ID number: ISI:000184157800003

PY - 2003

Y1 - 2003

N2 - Chains of H-bonded water intercalated bis-amide pairs were found in the structure of {[Cu(cdc)(2)(OH2)].H2O}(infinity). (1) (cdc(-) = carbamoyldicyanomethanide); specific hydration of one nitrile group of the cdc(-) ligands of 1 to give the previously unknown anion cyanomalonamidate (cyma(-)) as a ligand in [Cu(cyma)(2)].H2O is possible.

AB - Chains of H-bonded water intercalated bis-amide pairs were found in the structure of {[Cu(cdc)(2)(OH2)].H2O}(infinity). (1) (cdc(-) = carbamoyldicyanomethanide); specific hydration of one nitrile group of the cdc(-) ligands of 1 to give the previously unknown anion cyanomalonamidate (cyma(-)) as a ligand in [Cu(cyma)(2)].H2O is possible.

U2 - 10.1039/b306169h

DO - 10.1039/b306169h

M3 - Article

SN - 1477-9226

SP - 2639

EP - 2640

JO - Dalton Transactions

JF - Dalton Transactions

IS - 13

ER -

Structural characterisation of a water intercalated bis-ainide tecton and copper promoted monohydration of a dinitrile

Abstract

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