Structural characterisation of a water intercalated bis-ainide tecton and copper promoted monohydration of a dinitrile

J K Bjernemose, C J McKenzie, P R Raithby, S J Teat

Research output: Contribution to journalArticle

Abstract

Chains of H-bonded water intercalated bis-amide pairs were found in the structure of {[Cu(cdc)(2)(OH2)].H2O}(infinity). (1) (cdc(-) = carbamoyldicyanomethanide); specific hydration of one nitrile group of the cdc(-) ligands of 1 to give the previously unknown anion cyanomalonamidate (cyma(-)) as a ligand in [Cu(cyma)(2)].H2O is possible.
Original languageEnglish
Pages (from-to)2639-2640
Number of pages2
JournalDalton Transactions
Issue number13
DOIs
Publication statusPublished - 2003

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Copper
Ligands
Nitriles
Water
Amides
Hydration
Anions

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Structural characterisation of a water intercalated bis-ainide tecton and copper promoted monohydration of a dinitrile. / Bjernemose, J K; McKenzie, C J; Raithby, P R; Teat, S J.

In: Dalton Transactions, No. 13, 2003, p. 2639-2640.

Research output: Contribution to journalArticle

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AU - McKenzie, C J

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AU - Teat, S J

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AB - Chains of H-bonded water intercalated bis-amide pairs were found in the structure of {[Cu(cdc)(2)(OH2)].H2O}(infinity). (1) (cdc(-) = carbamoyldicyanomethanide); specific hydration of one nitrile group of the cdc(-) ligands of 1 to give the previously unknown anion cyanomalonamidate (cyma(-)) as a ligand in [Cu(cyma)(2)].H2O is possible.

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