Stoichiometric assembly of [Sb(PCy)3]2Li6·6HNMe 2·2C6H5Me; a highly fluxional antimony(III) phosphinidine complex containing Me2NH ligation of lithium

Michael A. Beswick; Jonathan M. Goodman; Christopher N. Harmer; Alexander D. Hopkins; Michael A. Paver; Paul R. Raithby; Andrew E.H. Wheatley; Dominic S. Wright

doi:10.1039/A703979D

Stoichiometric assembly of [Sb(PCy)₃]₂Li₆·6HNMe ₂·2C₆H₅Me; a highly fluxional antimony(III) phosphinidine complex containing Me₂NH ligation of lithium

Michael A. Beswick, Jonathan M. Goodman, Christopher N. Harmer, Alexander D. Hopkins, Michael A. Paver, Paul R. Raithby, Andrew E.H. Wheatley, Dominic S. Wright

University of Cambridge

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22 Citations (SciVal)

Abstract

All of the Me₂NH produced by the reaction of [Sb(NMe₂)₃] with CyP(H)Li (Cy = C₆H₁₁) coordinates the Li⁺ cations of the product [Sb(PCy)₃]₂Li₆·6HNMe ₂·2C₆H₅Me 1; the complex contains the first example of a group 15 metal phosphinidine anion {[Sb(PR)₃]^3-}.

Original language	English
Pages (from-to)	1879-1880
Number of pages	2
Journal	Chemical Communications
Volume	1997
Issue number	19
DOIs	https://doi.org/10.1039/A703979D
Publication status	Published - 31 Dec 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/A703979D

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Stoichiometric assembly of [Sb(PCy)₃]₂Li₆·6HNMe ₂·2C₆H₅Me; a highly fluxional antimony(III) phosphinidine complex containing Me₂NH ligation of lithium. / Beswick, Michael A.; Goodman, Jonathan M.; Harmer, Christopher N. et al.
In: Chemical Communications, Vol. 1997, No. 19, 31.12.1997, p. 1879-1880.

Research output: Contribution to journal › Article › peer-review

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title = "Stoichiometric assembly of [Sb(PCy)3]2Li6·6HNMe 2·2C6H5Me; a highly fluxional antimony(III) phosphinidine complex containing Me2NH ligation of lithium",

abstract = "All of the Me2NH produced by the reaction of [Sb(NMe2)3] with CyP(H)Li (Cy = C6H11) coordinates the Li+ cations of the product [Sb(PCy)3]2Li6·6HNMe 2·2C6H5Me 1; the complex contains the first example of a group 15 metal phosphinidine anion {[Sb(PR)3]3-}.",

author = "Beswick, {Michael A.} and Goodman, {Jonathan M.} and Harmer, {Christopher N.} and Hopkins, {Alexander D.} and Paver, {Michael A.} and Raithby, {Paul R.} and Wheatley, {Andrew E.H.} and Wright, {Dominic S.}",

year = "1997",

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doi = "10.1039/A703979D",

language = "English",

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T1 - Stoichiometric assembly of [Sb(PCy)3]2Li6·6HNMe 2·2C6H5Me; a highly fluxional antimony(III) phosphinidine complex containing Me2NH ligation of lithium

AU - Beswick, Michael A.

AU - Goodman, Jonathan M.

AU - Harmer, Christopher N.

AU - Hopkins, Alexander D.

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Wheatley, Andrew E.H.

AU - Wright, Dominic S.

PY - 1997/12/31

Y1 - 1997/12/31

N2 - All of the Me2NH produced by the reaction of [Sb(NMe2)3] with CyP(H)Li (Cy = C6H11) coordinates the Li+ cations of the product [Sb(PCy)3]2Li6·6HNMe 2·2C6H5Me 1; the complex contains the first example of a group 15 metal phosphinidine anion {[Sb(PR)3]3-}.

AB - All of the Me2NH produced by the reaction of [Sb(NMe2)3] with CyP(H)Li (Cy = C6H11) coordinates the Li+ cations of the product [Sb(PCy)3]2Li6·6HNMe 2·2C6H5Me 1; the complex contains the first example of a group 15 metal phosphinidine anion {[Sb(PR)3]3-}.

UR - http://www.scopus.com/inward/record.url?scp=0003105808&partnerID=8YFLogxK

U2 - 10.1039/A703979D

DO - 10.1039/A703979D

M3 - Article

AN - SCOPUS:0003105808

SN - 1359-7345

VL - 1997

SP - 1879

EP - 1880

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

Stoichiometric assembly of [Sb(PCy)₃]₂Li₆·6HNMe ₂·2C₆H₅Me; a highly fluxional antimony(III) phosphinidine complex containing Me₂NH ligation of lithium

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