Sterically induced cis isomerism in an Sb(III) imido dinier ; synthesis, structure and solution dynamics of [(Me2N)Sb(μ-NDipp)]2 (Dipp = 2,6-Pri26H3)

Michael A. Beswick, Christopher N. Harmer, Alexander D. Hopkins, Michael A. Paver, Paul R. Raithby, Dominic S. Wright

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The reaction of [Sb(NMe2)3] with the sterically bulky amine [DippNH2] gives the unusual cis dimer [(Me2N)Sb(μ-NDipp)]2 1, containing a puckered Sb2N2 core. 1H NMR studies show that the cis conformation is retained in solution.

Original languageEnglish
Pages (from-to)745-748
Number of pages4
JournalPolyhedron
Volume17
Issue number5-6
DOIs
Publication statusPublished - 1998

Keywords

  • Cis isomerism
  • Puckered SbN core
  • Sb(III) imido dimer

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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