Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition of nucleophiles to divinyl ketones

Andrew C Silvanus; B J Groombridge; B I Andrews; Gabriele Kociok-Kohn; David R Carbery

doi:10.1021/jo101713d

Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition of nucleophiles to divinyl ketones

Andrew C Silvanus, B J Groombridge, B I Andrews, Gabriele Kociok-Kohn, David R Carbery

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

37 Citations (SciVal)

Abstract

Functionalized cyclohexanones are formed in excellent yield and diastereoselectivity from a phase transfer catalyzed double addition of active methylene pronucleophiles to non-symmetrical divinyl ketones.

Original language	English
Pages (from-to)	7491-7493
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	75
Issue number	21
DOIs	https://doi.org/10.1021/jo101713d
Publication status	Published - 5 Nov 2010

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@article{f10cafedcd1c432a9a48256b5d4cea14,

title = "Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition of nucleophiles to divinyl ketones",

abstract = "Functionalized cyclohexanones are formed in excellent yield and diastereoselectivity from a phase transfer catalyzed double addition of active methylene pronucleophiles to non-symmetrical divinyl ketones.",

author = "Silvanus, \{Andrew C\} and Groombridge, \{B J\} and Andrews, \{B I\} and Gabriele Kociok-Kohn and Carbery, \{David R\}",

year = "2010",

month = nov,

day = "5",

doi = "10.1021/jo101713d",

language = "English",

volume = "75",

pages = "7491--7493",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition of nucleophiles to divinyl ketones

AU - Silvanus, Andrew C

AU - Groombridge, B J

AU - Andrews, B I

AU - Kociok-Kohn, Gabriele

AU - Carbery, David R

PY - 2010/11/5

Y1 - 2010/11/5

N2 - Functionalized cyclohexanones are formed in excellent yield and diastereoselectivity from a phase transfer catalyzed double addition of active methylene pronucleophiles to non-symmetrical divinyl ketones.

AB - Functionalized cyclohexanones are formed in excellent yield and diastereoselectivity from a phase transfer catalyzed double addition of active methylene pronucleophiles to non-symmetrical divinyl ketones.

UR - https://www.scopus.com/pages/publications/78049516353

UR - http://dx.doi.org/10.1021/jo101713d

U2 - 10.1021/jo101713d

DO - 10.1021/jo101713d

M3 - Article

SN - 0022-3263

VL - 75

SP - 7491

EP - 7493

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 21

ER -

Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition of nucleophiles to divinyl ketones

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