Stepwise reduction of [Fe4(CO)13]2- by successive methylation and hydrogenation; the x-ray crystal structures of [Fe4(CO)12COMe]- and [Fe4H(CO ) 12COMe]

Peter A. Dawson; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby

doi:10.1039/c39800000781

Stepwise reduction of [Fe₄(CO)₁₃]^2- by successive methylation and hydrogenation; the x-ray crystal structures of [Fe₄(CO)₁₂COMe]^- and [Fe₄H(CO ) ₁₂COMe]

Peter A. Dawson, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of [Fe₄(CO)₁₃]^2- with [Me₃O][BF₄] leads to the reduction of a CO ligand to give [Fe₄(CO)₁₂-COMe]^-, where the COMe ligand μ₃-caps a face of the Fe₄ tetrahedron ; subsequent protonation with HSO₃F yields [Fe₄H(CO)₁₂COMe], in which the COMe co-ordinates to the Fe₄ 'butterfly' via C and O atoms; the structures have been confirmed by X-ray analyses.

Original language	English
Pages (from-to)	781-783
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/c39800000781
Publication status	Published - 31 Dec 1980

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Molecular Medicine

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10.1039/c39800000781

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Stepwise reduction of [Fe₄(CO)₁₃]^2- by successive methylation and hydrogenation; the x-ray crystal structures of [Fe₄(CO)₁₂COMe]^- and [Fe₄H(CO ) ₁₂COMe]. / Dawson, Peter A.; Johnson, Brian F.G.; Lewis, Jack et al.
In: Journal of the Chemical Society, Chemical Communications, No. 16, 31.12.1980, p. 781-783.

Research output: Contribution to journal › Article › peer-review

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title = "Stepwise reduction of [Fe4(CO)13]2- by successive methylation and hydrogenation; the x-ray crystal structures of [Fe4(CO)12COMe]- and [Fe4H(CO ) 12COMe]",

abstract = "The reaction of [Fe4(CO)13]2- with [Me3O][BF4] leads to the reduction of a CO ligand to give [Fe4(CO)12-COMe]-, where the COMe ligand μ3-caps a face of the Fe4 tetrahedron ; subsequent protonation with HSO3F yields [Fe4H(CO)12COMe], in which the COMe co-ordinates to the Fe4 'butterfly' via C and O atoms; the structures have been confirmed by X-ray analyses.",

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AU - Dawson, Peter A.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

PY - 1980/12/31

Y1 - 1980/12/31

N2 - The reaction of [Fe4(CO)13]2- with [Me3O][BF4] leads to the reduction of a CO ligand to give [Fe4(CO)12-COMe]-, where the COMe ligand μ3-caps a face of the Fe4 tetrahedron ; subsequent protonation with HSO3F yields [Fe4H(CO)12COMe], in which the COMe co-ordinates to the Fe4 'butterfly' via C and O atoms; the structures have been confirmed by X-ray analyses.

AB - The reaction of [Fe4(CO)13]2- with [Me3O][BF4] leads to the reduction of a CO ligand to give [Fe4(CO)12-COMe]-, where the COMe ligand μ3-caps a face of the Fe4 tetrahedron ; subsequent protonation with HSO3F yields [Fe4H(CO)12COMe], in which the COMe co-ordinates to the Fe4 'butterfly' via C and O atoms; the structures have been confirmed by X-ray analyses.

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DO - 10.1039/c39800000781

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ER -

Stepwise reduction of [Fe₄(CO)₁₃]^2- by successive methylation and hydrogenation; the x-ray crystal structures of [Fe₄(CO)₁₂COMe]^- and [Fe₄H(CO ) ₁₂COMe]

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