Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η3-C5H5)[μ-N=C(NMe 2)2]}2] and [{Sn[S(CH2)3SC(R)][μ-N=C(NMe2) 2]}2] (R = H or SiMe3)

Andrew J. Edwards; Michael A. Paver; Paul R. Raithby; Moira Ann Rennie; Christopher A. Russell; Dominic S. Wright

doi:10.1039/DT9950001587

Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] and [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃)

Andrew J. Edwards
, Michael A. Paver
, Paul R. Raithby
, Moira Ann Rennie
, Christopher A. Russell
, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Nucleophilic substitution of Sn(C₅H₅)₂ with LiN=C(NMe₂)₂ led to the monosubstitution of only one C₅H₅ ligand yielding dimeric [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] in which the remaining C₅H₅ group can be further substituted by reactions with lithiated 1,3-dithianes to give the dimeric mixed-ligand imino-1,3-dithiane complexes [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃).

Original language	English
Pages (from-to)	1587-1591
Number of pages	5
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	10
DOIs	https://doi.org/10.1039/DT9950001587
Publication status	Published - 1 Jan 1995

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1039/DT9950001587

Fingerprint

Dive into the research topics of 'Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] and [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃)'. Together they form a unique fingerprint.

Cite this

Edwards, A. J., Paver, M. A., Raithby, P. R., Rennie, M. A., Russell, C. A., & Wright, D. S. (1995). Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] and [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃). Journal of the Chemical Society, Dalton Transactions, (10), 1587-1591. https://doi.org/10.1039/DT9950001587

Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] and [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃). / Edwards, Andrew J.; Paver, Michael A.; Raithby, Paul R. et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 10, 01.01.1995, p. 1587-1591.

Research output: Contribution to journal › Article › peer-review

Edwards, AJ, Paver, MA, Raithby, PR, Rennie, MA, Russell, CA & Wright, DS 1995, 'Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] and [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃)', Journal of the Chemical Society, Dalton Transactions, no. 10, pp. 1587-1591. https://doi.org/10.1039/DT9950001587

Edwards AJ, Paver MA, Raithby PR, Rennie MA, Russell CA, Wright DS. Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] and [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃). Journal of the Chemical Society, Dalton Transactions. 1995 Jan 1;(10):1587-1591. doi: 10.1039/DT9950001587

@article{b859c6d17f4b4bf2833a0fe3f115a803,

title = "Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [\{Sn(η3-C5H5)[μ-N=C(NMe 2)2]\}2] and [\{Sn[S(CH2)3SC(R)][μ-N=C(NMe2) 2]\}2] (R = H or SiMe3)",

abstract = "Nucleophilic substitution of Sn(C5H5)2 with LiN=C(NMe2)2 led to the monosubstitution of only one C5H5 ligand yielding dimeric [\{Sn(η3-C5H5)[μ-N=C(NMe 2)2]\}2] in which the remaining C5H5 group can be further substituted by reactions with lithiated 1,3-dithianes to give the dimeric mixed-ligand imino-1,3-dithiane complexes [\{Sn[S(CH2)3SC(R)][μ-N=C(NMe2) 2]\}2] (R = H or SiMe3).",

author = "Edwards, \{Andrew J.\} and Paver, \{Michael A.\} and Raithby, \{Paul R.\} and Rennie, \{Moira Ann\} and Russell, \{Christopher A.\} and Wright, \{Dominic S.\}",

year = "1995",

month = jan,

day = "1",

doi = "10.1039/DT9950001587",

language = "English",

pages = "1587--1591",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η3-C5H5)[μ-N=C(NMe 2)2]}2] and [{Sn[S(CH2)3SC(R)][μ-N=C(NMe2) 2]}2] (R = H or SiMe3)

AU - Edwards, Andrew J.

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Rennie, Moira Ann

AU - Russell, Christopher A.

AU - Wright, Dominic S.

PY - 1995/1/1

Y1 - 1995/1/1

N2 - Nucleophilic substitution of Sn(C5H5)2 with LiN=C(NMe2)2 led to the monosubstitution of only one C5H5 ligand yielding dimeric [{Sn(η3-C5H5)[μ-N=C(NMe 2)2]}2] in which the remaining C5H5 group can be further substituted by reactions with lithiated 1,3-dithianes to give the dimeric mixed-ligand imino-1,3-dithiane complexes [{Sn[S(CH2)3SC(R)][μ-N=C(NMe2) 2]}2] (R = H or SiMe3).

AB - Nucleophilic substitution of Sn(C5H5)2 with LiN=C(NMe2)2 led to the monosubstitution of only one C5H5 ligand yielding dimeric [{Sn(η3-C5H5)[μ-N=C(NMe 2)2]}2] in which the remaining C5H5 group can be further substituted by reactions with lithiated 1,3-dithianes to give the dimeric mixed-ligand imino-1,3-dithiane complexes [{Sn[S(CH2)3SC(R)][μ-N=C(NMe2) 2]}2] (R = H or SiMe3).

UR - https://www.scopus.com/pages/publications/37049089755

U2 - 10.1039/DT9950001587

DO - 10.1039/DT9950001587

M3 - Article

AN - SCOPUS:37049089755

SN - 1472-7773

SP - 1587

EP - 1591

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 10

ER -