Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η3-C5H5)[μ-N=C(NMe 2)2]}2] and [{Sn[S(CH2)3SC(R)][μ-N=C(NMe2) 2]}2] (R = H or SiMe3)

Andrew J. Edwards; Michael A. Paver; Paul R. Raithby; Moira Ann Rennie; Christopher A. Russell; Dominic S. Wright

doi:10.1039/DT9950001587

Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] and [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃)

Andrew J. Edwards, Michael A. Paver, Paul R. Raithby, Moira Ann Rennie, Christopher A. Russell, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Nucleophilic substitution of Sn(C₅H₅)₂ with LiN=C(NMe₂)₂ led to the monosubstitution of only one C₅H₅ ligand yielding dimeric [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] in which the remaining C₅H₅ group can be further substituted by reactions with lithiated 1,3-dithianes to give the dimeric mixed-ligand imino-1,3-dithiane complexes [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃).

Original language	English
Pages (from-to)	1587-1591
Number of pages	5
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	10
DOIs	https://doi.org/10.1039/DT9950001587
Publication status	Published - 1 Jan 1995

ASJC Scopus subject areas

General Chemistry

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Edwards, A. J., Paver, M. A., Raithby, P. R., Rennie, M. A., Russell, C. A., & Wright, D. S. (1995). Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] and [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃). Journal of the Chemical Society, Dalton Transactions, (10), 1587-1591. https://doi.org/10.1039/DT9950001587

Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] and [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃). / Edwards, Andrew J.; Paver, Michael A.; Raithby, Paul R. et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 10, 01.01.1995, p. 1587-1591.

Research output: Contribution to journal › Article › peer-review

Edwards, AJ, Paver, MA, Raithby, PR, Rennie, MA, Russell, CA & Wright, DS 1995, 'Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] and [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃)', Journal of the Chemical Society, Dalton Transactions, no. 10, pp. 1587-1591. https://doi.org/10.1039/DT9950001587

Edwards AJ, Paver MA, Raithby PR, Rennie MA, Russell CA, Wright DS. Step-wise nucleophilic substitution of bis(cyclopentadienyl)-tin(II); Synthesis and structural characterisation of [{Sn(η³-C₅H₅)[μ-N=C(NMe ₂)₂]}₂] and [{Sn[S(CH₂)₃SC(R)][μ-N=C(NMe₂) ₂]}₂] (R = H or SiMe₃). Journal of the Chemical Society, Dalton Transactions. 1995 Jan 1;(10):1587-1591. doi: 10.1039/DT9950001587

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abstract = "Nucleophilic substitution of Sn(C5H5)2 with LiN=C(NMe2)2 led to the monosubstitution of only one C5H5 ligand yielding dimeric [{Sn(η3-C5H5)[μ-N=C(NMe 2)2]}2] in which the remaining C5H5 group can be further substituted by reactions with lithiated 1,3-dithianes to give the dimeric mixed-ligand imino-1,3-dithiane complexes [{Sn[S(CH2)3SC(R)][μ-N=C(NMe2) 2]}2] (R = H or SiMe3).",

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AB - Nucleophilic substitution of Sn(C5H5)2 with LiN=C(NMe2)2 led to the monosubstitution of only one C5H5 ligand yielding dimeric [{Sn(η3-C5H5)[μ-N=C(NMe 2)2]}2] in which the remaining C5H5 group can be further substituted by reactions with lithiated 1,3-dithianes to give the dimeric mixed-ligand imino-1,3-dithiane complexes [{Sn[S(CH2)3SC(R)][μ-N=C(NMe2) 2]}2] (R = H or SiMe3).

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