Standard Methodology for Evaluating Membrane Performance in Osmotically Driven Membrane Processes

Tzahi Y. Cath, Menachem Elimelech, Jeffrey R. McCutcheon, Robert L. McGinnis, Andrea Achilli, Daniel Anastasio, Adam R. Brady, Amy E. Childress, Isaac V. Farr, Nathan T. Hancock, Jason Lampi, Long D. Nghiem, Ming Xie, Ngai Yin Yip

Research output: Contribution to journalArticle

257 Citations (Scopus)

Abstract

Osmotically driven membrane processes (ODMPs) such as forward osmosis (FO) and pressure retarded osmosis (PRO) are extensively investigated for utilization in a broad range of applications. In ODMPs, the operating conditions and membrane properties play more critical roles in mass transport and process performance than in pressure-driven membrane processes. Search of the literature reveals that ODMP membranes, especially newly developed ones, are tested under different temperatures, draw solution compositions and concentrations, flow rates, and pressures. In order to compare different membranes, it is important to develop standard protocols for testing of membranes for ODMPs. In this article we present a standard methodology for testing of ODMP membranes based on experience gained and operating conditions used in FO and PRO studies in recent years. A round-robin testing of two commercial membranes in seven independent laboratories revealed that water flux and membrane permeability coefficients were similar when participants performed the experiments and calculations using the same protocols. The thin film composite polyamide membrane exhibited higher water and salt permeability than the asymmetric cellulose-based membrane, but results with the high permeability thin-film composite membrane were more scattered. While salt rejection results in RO mode were relatively similar, salt permeability coefficients for both membranes in FO mode were more varied. Results suggest that high permeability ODMP membranes should be tested at lower hydraulic pressure in RO mode and that RO testing be conducted with the same membrane sample used for testing in FO mode.

Original languageEnglish
Pages (from-to)31-38
Number of pages8
JournalDesalination
Volume312
Early online date10 Aug 2012
DOIs
Publication statusPublished - 1 Mar 2013

Keywords

  • Desalination
  • Forward osmosis (FO)
  • Osmotic dilution (ODN)
  • Osmotically driven membrane process (ODMP)
  • Pressure retarded osmosis (PRO)
  • Water reclamation

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Mechanical Engineering
  • Chemistry(all)
  • Materials Science(all)
  • Water Science and Technology

Cite this

Cath, T. Y., Elimelech, M., McCutcheon, J. R., McGinnis, R. L., Achilli, A., Anastasio, D., Brady, A. R., Childress, A. E., Farr, I. V., Hancock, N. T., Lampi, J., Nghiem, L. D., Xie, M., & Yip, N. Y. (2013). Standard Methodology for Evaluating Membrane Performance in Osmotically Driven Membrane Processes. Desalination, 312, 31-38. https://doi.org/10.1016/j.desal.2012.07.005