Stable cellulose nanofibril microcapsules from Pickering emulsion templates

Hui Shi Huishi; Kazi M.Zakir Hossain; Davide Califano; Ekanem Ekanem; Ciaran Callaghan; Janet L Scott; Davide Mattia; Karen Edler

doi:10.1021/acs.langmuir.1c03025

Stable cellulose nanofibril microcapsules from Pickering emulsion templates

Hui Shi Huishi, Kazi M.Zakir Hossain, Davide Califano, Ekanem Ekanem, Ciaran Callaghan, Janet L Scott, Davide Mattia, Karen Edler

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Abstract

Electrostatic attractions are essential in any complex formation between the nanofibrils of the opposite charge for a specific application, such as microcapsule production. Here, we used cationized cellulose nanofibril (CCNF)-stabilized Pickering emulsions (PEs) as templates, and the electrostatic interactions were induced by adding oxidized cellulose nanofibrils (OCNFs) at the oil–water interface to form microcapsules (MCs). The oppositely charged cellulose nanofibrils enhanced the solidity of interfaces, allowing the encapsulation of Nile red (NR) in sunflower oil droplets. Microcapsules exhibited a low and controlled release of NR at room temperature. Furthermore, membrane emulsification was employed to scale up the preparation of microcapsules with sunflower oil (SFO) encapsulated by CCNF/OCNF complex networks.

Original language	English
Pages (from-to)	3370-3379
Number of pages	10
Journal	Langmuir
Volume	38
Issue number	11
Early online date	9 Mar 2022
DOIs	https://doi.org/10.1021/acs.langmuir.1c03025
Publication status	Published - 22 Mar 2022

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This document is the Accepted Manuscript version of a Published Work that appeared in final form in Langmuir, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.langmuir.1c03025
Accepted author manuscript, 909 KBLicence: CC BY

Cite this

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title = "Stable cellulose nanofibril microcapsules from Pickering emulsion templates",

abstract = "Electrostatic attractions are essential in any complex formation between the nanofibrils of the opposite charge for a specific application, such as microcapsule production. Here, we used cationized cellulose nanofibril (CCNF)-stabilized Pickering emulsions (PEs) as templates, and the electrostatic interactions were induced by adding oxidized cellulose nanofibrils (OCNFs) at the oil–water interface to form microcapsules (MCs). The oppositely charged cellulose nanofibrils enhanced the solidity of interfaces, allowing the encapsulation of Nile red (NR) in sunflower oil droplets. Microcapsules exhibited a low and controlled release of NR at room temperature. Furthermore, membrane emulsification was employed to scale up the preparation of microcapsules with sunflower oil (SFO) encapsulated by CCNF/OCNF complex networks.",

author = "Huishi, {Hui Shi} and Hossain, {Kazi M.Zakir} and Davide Califano and Ekanem Ekanem and Ciaran Callaghan and Scott, {Janet L} and Davide Mattia and Karen Edler",

note = "Funding Information: The authors would like to thank the EPSRC for funding this project (Grant EP/P027490/1). The authors thank Diana Lednitzky and Philip Fletcher of the Material and Chemical Characterisation Facility (MC) at the University of Bath for helping with TEM imaging. Data supporting this work is freely accessible in the Bath research data archive system at DOI: 10.15125/BATH-01110. 2 Publisher Copyright: {\textcopyright} 2022 American Chemical Society. All rights reserved.",

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AU - Huishi, Hui Shi

AU - Hossain, Kazi M.Zakir

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AU - Ekanem, Ekanem

AU - Callaghan, Ciaran

AU - Scott, Janet L

AU - Mattia, Davide

AU - Edler, Karen

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N2 - Electrostatic attractions are essential in any complex formation between the nanofibrils of the opposite charge for a specific application, such as microcapsule production. Here, we used cationized cellulose nanofibril (CCNF)-stabilized Pickering emulsions (PEs) as templates, and the electrostatic interactions were induced by adding oxidized cellulose nanofibrils (OCNFs) at the oil–water interface to form microcapsules (MCs). The oppositely charged cellulose nanofibrils enhanced the solidity of interfaces, allowing the encapsulation of Nile red (NR) in sunflower oil droplets. Microcapsules exhibited a low and controlled release of NR at room temperature. Furthermore, membrane emulsification was employed to scale up the preparation of microcapsules with sunflower oil (SFO) encapsulated by CCNF/OCNF complex networks.

AB - Electrostatic attractions are essential in any complex formation between the nanofibrils of the opposite charge for a specific application, such as microcapsule production. Here, we used cationized cellulose nanofibril (CCNF)-stabilized Pickering emulsions (PEs) as templates, and the electrostatic interactions were induced by adding oxidized cellulose nanofibrils (OCNFs) at the oil–water interface to form microcapsules (MCs). The oppositely charged cellulose nanofibrils enhanced the solidity of interfaces, allowing the encapsulation of Nile red (NR) in sunflower oil droplets. Microcapsules exhibited a low and controlled release of NR at room temperature. Furthermore, membrane emulsification was employed to scale up the preparation of microcapsules with sunflower oil (SFO) encapsulated by CCNF/OCNF complex networks.

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Stable cellulose nanofibril microcapsules from Pickering emulsion templates

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