Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative

Anne Almesaker; Patrick Gamez; Jan Reedijk; Janet L. Scott; Leone Spiccia; Simon J Teat

doi:10.1039/B902907A

Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative

Anne Almesaker
, Patrick Gamez
, Jan Reedijk
, Janet L. Scott
, Leone Spiccia
, Simon J Teat

Research output: Contribution to journal › Article › peer-review

11 Citations (SciVal)

Abstract

The copper(II) coordination compound of an N-functionalised derivative of tris(2-aminoethyl)amine forms a cavity that is an excellent fluoride ion host, generating a Cu–F entity with a very short distance (182 pm) and characterised by a fluoride ion devoid of any additional intermolecular interactions.

Original language	English
Pages (from-to)	4077-4080
Journal	Dalton Transactions
Volume	2009
Issue number	21
DOIs	https://doi.org/10.1039/B902907A
Publication status	Published - 2009

Access to Document

10.1039/B902907A

Cite this

@article{f9e03a3a67504d528d0ccf6c463125a0,

title = "Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative",

abstract = "The copper(II) coordination compound of an N-functionalised derivative of tris(2-aminoethyl)amine forms a cavity that is an excellent fluoride ion host, generating a Cu{\textendash}F entity with a very short distance (182 pm) and characterised by a fluoride ion devoid of any additional intermolecular interactions.",

author = "Anne Almesaker and Patrick Gamez and Jan Reedijk and Scott, \{Janet L.\} and Leone Spiccia and Teat, \{Simon J\}",

year = "2009",

doi = "10.1039/B902907A",

language = "English",

volume = "2009",

pages = "4077--4080",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "21",

}

TY - JOUR

T1 - Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative

AU - Almesaker, Anne

AU - Gamez, Patrick

AU - Reedijk, Jan

AU - Scott, Janet L.

AU - Spiccia, Leone

AU - Teat, Simon J

PY - 2009

Y1 - 2009

N2 - The copper(II) coordination compound of an N-functionalised derivative of tris(2-aminoethyl)amine forms a cavity that is an excellent fluoride ion host, generating a Cu–F entity with a very short distance (182 pm) and characterised by a fluoride ion devoid of any additional intermolecular interactions.

AB - The copper(II) coordination compound of an N-functionalised derivative of tris(2-aminoethyl)amine forms a cavity that is an excellent fluoride ion host, generating a Cu–F entity with a very short distance (182 pm) and characterised by a fluoride ion devoid of any additional intermolecular interactions.

UR - https://www.scopus.com/pages/publications/65949121627

UR - http://dx.doi.org/10.1039/B902907A

U2 - 10.1039/B902907A

DO - 10.1039/B902907A

M3 - Article

SN - 1477-9226

VL - 2009

SP - 4077

EP - 4080

JO - Dalton Transactions

JF - Dalton Transactions

IS - 21

ER -

Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative

Abstract

Access to Document

Other files and links

Fingerprint

Cite this