Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative

Anne Almesaker; Patrick Gamez; Jan Reedijk; Janet L. Scott; Leone Spiccia; Simon J Teat

doi:10.1039/B902907A

Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative

Anne Almesaker, Patrick Gamez, Jan Reedijk, Janet L. Scott, Leone Spiccia, Simon J Teat

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11 Citations (SciVal)

Abstract

The copper(II) coordination compound of an N-functionalised derivative of tris(2-aminoethyl)amine forms a cavity that is an excellent fluoride ion host, generating a Cu–F entity with a very short distance (182 pm) and characterised by a fluoride ion devoid of any additional intermolecular interactions.

Original language	English
Pages (from-to)	4077-4080
Journal	Dalton Transactions
Volume	2009
Issue number	21
DOIs	https://doi.org/10.1039/B902907A
Publication status	Published - 2009

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title = "Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative",

abstract = "The copper(II) coordination compound of an N-functionalised derivative of tris(2-aminoethyl)amine forms a cavity that is an excellent fluoride ion host, generating a Cu–F entity with a very short distance (182 pm) and characterised by a fluoride ion devoid of any additional intermolecular interactions.",

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AU - Almesaker, Anne

AU - Gamez, Patrick

AU - Reedijk, Jan

AU - Scott, Janet L.

AU - Spiccia, Leone

AU - Teat, Simon J

PY - 2009

Y1 - 2009

N2 - The copper(II) coordination compound of an N-functionalised derivative of tris(2-aminoethyl)amine forms a cavity that is an excellent fluoride ion host, generating a Cu–F entity with a very short distance (182 pm) and characterised by a fluoride ion devoid of any additional intermolecular interactions.

AB - The copper(II) coordination compound of an N-functionalised derivative of tris(2-aminoethyl)amine forms a cavity that is an excellent fluoride ion host, generating a Cu–F entity with a very short distance (182 pm) and characterised by a fluoride ion devoid of any additional intermolecular interactions.

UR - https://www.scopus.com/pages/publications/65949121627

UR - http://dx.doi.org/10.1039/B902907A

U2 - 10.1039/B902907A

DO - 10.1039/B902907A

M3 - Article

SN - 1477-9226

VL - 2009

SP - 4077

EP - 4080

JO - Dalton Transactions

JF - Dalton Transactions

IS - 21

ER -

Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative

Abstract

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