Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative

Anne Almesaker, Patrick Gamez, Jan Reedijk, Janet L. Scott, Leone Spiccia, Simon J Teat

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The copper(II) coordination compound of an N-functionalised derivative of tris(2-aminoethyl)amine forms a cavity that is an excellent fluoride ion host, generating a Cu–F entity with a very short distance (182 pm) and characterised by a fluoride ion devoid of any additional intermolecular interactions.
Original languageEnglish
Pages (from-to)4077-4080
JournalDalton Transactions
Volume2009
Issue number21
DOIs
Publication statusPublished - 2009

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