Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative

Anne Almesaker, Patrick Gamez, Jan Reedijk, Janet L. Scott, Leone Spiccia, Simon J Teat

Research output: Contribution to journalArticle

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Abstract

The copper(II) coordination compound of an N-functionalised derivative of tris(2-aminoethyl)amine forms a cavity that is an excellent fluoride ion host, generating a Cu–F entity with a very short distance (182 pm) and characterised by a fluoride ion devoid of any additional intermolecular interactions.
LanguageEnglish
Pages4077-4080
JournalDalton Transactions
Volume2009
Issue number21
DOIs
StatusPublished - 2009

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Copper compounds
Fluorides
Stabilization
Ions
Derivatives
Copper
tris(2-aminoethyl)amine

Cite this

Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative. / Almesaker, Anne; Gamez, Patrick; Reedijk, Jan; Scott, Janet L.; Spiccia, Leone; Teat, Simon J.

In: Dalton Transactions, Vol. 2009, No. 21, 2009, p. 4077-4080.

Research output: Contribution to journalArticle

Almesaker, Anne ; Gamez, Patrick ; Reedijk, Jan ; Scott, Janet L. ; Spiccia, Leone ; Teat, Simon J. / Stabilisation of a very short Cu-F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative. In: Dalton Transactions. 2009 ; Vol. 2009, No. 21. pp. 4077-4080
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