Stabilisation of a heptamethine cyanine dye by rotaxane encapsulation

C M Simon Yau, Sofia I Pascu, Susan A Odom, John E Warren, Eric J F Klotz, Michael J Frampton, Charlotte C Williams, Veaceslav Coropceanu, Marina K Kuimova, David Phillips, Stephen Barlow, Jean-Luc Brédas, Seth R Marder, Val Millar, Harry L Anderson

Research output: Contribution to journalArticle

50 Citations (Scopus)

Abstract

The crystal structure of a cyanine dye rotaxane shows that the cyclodextrin is tightly threaded round the polymethine bridge of the dye; encapsulation dramatically increases the kinetic chemical stability of the radicals formed on oxidation and reduction of the dye, making it possible to observe the rotaxane radical dication by ESR and UV-vis-NIR spectroscopy.
Original languageEnglish
Pages (from-to)2897-2899
Number of pages3
JournalChemical Communications
Volume2008
Issue number25
DOIs
Publication statusPublished - 2008

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    Yau, C. M. S., Pascu, S. I., Odom, S. A., Warren, J. E., Klotz, E. J. F., Frampton, M. J., Williams, C. C., Coropceanu, V., Kuimova, M. K., Phillips, D., Barlow, S., Brédas, J-L., Marder, S. R., Millar, V., & Anderson, H. L. (2008). Stabilisation of a heptamethine cyanine dye by rotaxane encapsulation. Chemical Communications, 2008(25), 2897-2899. https://doi.org/10.1039/b802728e