Spherical hydroxyapatite nanoparticle scaffolds for reduced lead release from damaged perovskite solar cells

Muhamad Z. Mokhtar; Amal Altujjar; Bing Wang; Qian Chen; Jack Chun Ren Ke; Rongsheng Cai; Nourdine Zibouche; Ben F. Spencer; Janet Jacobs; Andrew G. Thomas; David Hall; Sarah J. Haigh; David J. Lewis; Richard Curry; M. Saiful Islam; Brian R. Saunders

doi:10.1038/s43246-022-00299-3

Spherical hydroxyapatite nanoparticle scaffolds for reduced lead release from damaged perovskite solar cells

Muhamad Z. Mokhtar, Amal Altujjar, Bing Wang, Qian Chen, Jack Chun Ren Ke, Rongsheng Cai, Nourdine Zibouche, Ben F. Spencer, Janet Jacobs, Andrew G. Thomas, David Hall, Sarah J. Haigh, David J. Lewis, Richard Curry, M. Saiful Islam, Brian R. Saunders

Research output: Contribution to journal › Article › peer-review

4 Citations (SciVal)

Abstract

Perovskite solar cells continue to attract interest due to their facile preparation and high power conversion efficiencies. However, the highest efficiency perovskite solar cells inevitably contain lead, which raises concerns over contamination of drinking water when a solar module is broken and then flooded. We previously showed that conventional synthetic hydroxyapatite (HAP) nanoparticles could capture some of the lead from broken solar cells, but the amount of lead released was well above the safe drinking water level. Here, we modify the HAP synthesis to prepare new spherical-HAP (s-HAP) nanoparticles with a 60% increase in the Pb absorption capacity. We blend s-HAPs with TiO₂ nanoparticles to construct mixed scaffolds and investigate their effect on (FAPbI₃)_0.97(MAPbBr₃)_0.03 solar cell performance and lead capture. Replacement of 80% of the TiO₂ nanoparticles with s-HAP causes the power conversion efficiency to increase from 18.61% to 20.32% as a result of decreased charge carrier recombination. Lead contamination of water from devices subjected to simulated hail damage followed by flooding is shown to decrease exponentially with increasing s-HAP content. The lead concentration in water after 24 h is below the US safe water drinking limit.

Original language	English
Article number	77
Journal	Communications Materials
Volume	3
Issue number	1
DOIs	https://doi.org/10.1038/s43246-022-00299-3
Publication status	Published - 9 Oct 2022

Bibliographical note

Funding Information:
We would like to thank the EPSRC for funding (EP/R020590/1). This work including TEM access was supported by the Henry Royce Institute for Advanced Materials, funded through EPSRC grants EP/R00661X/1, EP/S019367/1, EP/P025021/1 and EP/P025498/1. S.J.H. acknowledges the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (Grant ERC-2016-STG-EvoluTEM-715502). R.C. and S.J.H. would like to thank the UK Catalysis Hub for resources and support provided via the membership of the UK Catalysis Hub Consortium and funded by EPSRC grant: EP/R027129/1. We gratefully acknowledge supercomputer resources via the MCC/Archer HPC consortium (EP/R029431/1).

ASJC Scopus subject areas

General Materials Science
Mechanics of Materials

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1038/s43246-022-00299-3Licence: CC BY

Cite this

Mokhtar, M. Z., Altujjar, A., Wang, B., Chen, Q., Ke, J. C. R., Cai, R., Zibouche, N., Spencer, B. F., Jacobs, J., Thomas, A. G., Hall, D., Haigh, S. J., Lewis, D. J., Curry, R., Islam, M. S., & Saunders, B. R. (2022). Spherical hydroxyapatite nanoparticle scaffolds for reduced lead release from damaged perovskite solar cells. Communications Materials, 3(1), Article 77. https://doi.org/10.1038/s43246-022-00299-3

Mokhtar, MZ, Altujjar, A, Wang, B, Chen, Q, Ke, JCR, Cai, R, Zibouche, N, Spencer, BF, Jacobs, J, Thomas, AG, Hall, D, Haigh, SJ, Lewis, DJ, Curry, R, Islam, MS & Saunders, BR 2022, 'Spherical hydroxyapatite nanoparticle scaffolds for reduced lead release from damaged perovskite solar cells', Communications Materials, vol. 3, no. 1, 77. https://doi.org/10.1038/s43246-022-00299-3

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title = "Spherical hydroxyapatite nanoparticle scaffolds for reduced lead release from damaged perovskite solar cells",

abstract = "Perovskite solar cells continue to attract interest due to their facile preparation and high power conversion efficiencies. However, the highest efficiency perovskite solar cells inevitably contain lead, which raises concerns over contamination of drinking water when a solar module is broken and then flooded. We previously showed that conventional synthetic hydroxyapatite (HAP) nanoparticles could capture some of the lead from broken solar cells, but the amount of lead released was well above the safe drinking water level. Here, we modify the HAP synthesis to prepare new spherical-HAP (s-HAP) nanoparticles with a 60% increase in the Pb absorption capacity. We blend s-HAPs with TiO2 nanoparticles to construct mixed scaffolds and investigate their effect on (FAPbI3)0.97(MAPbBr3)0.03 solar cell performance and lead capture. Replacement of 80% of the TiO2 nanoparticles with s-HAP causes the power conversion efficiency to increase from 18.61% to 20.32% as a result of decreased charge carrier recombination. Lead contamination of water from devices subjected to simulated hail damage followed by flooding is shown to decrease exponentially with increasing s-HAP content. The lead concentration in water after 24 h is below the US safe water drinking limit.",

author = "Mokhtar, {Muhamad Z.} and Amal Altujjar and Bing Wang and Qian Chen and Ke, {Jack Chun Ren} and Rongsheng Cai and Nourdine Zibouche and Spencer, {Ben F.} and Janet Jacobs and Thomas, {Andrew G.} and David Hall and Haigh, {Sarah J.} and Lewis, {David J.} and Richard Curry and Islam, {M. Saiful} and Saunders, {Brian R.}",

note = "Funding Information: We would like to thank the EPSRC for funding (EP/R020590/1). This work including TEM access was supported by the Henry Royce Institute for Advanced Materials, funded through EPSRC grants EP/R00661X/1, EP/S019367/1, EP/P025021/1 and EP/P025498/1. S.J.H. acknowledges the European Research Council (ERC) under the European Union{\textquoteright}s Horizon 2020 research and innovation programme (Grant ERC-2016-STG-EvoluTEM-715502). R.C. and S.J.H. would like to thank the UK Catalysis Hub for resources and support provided via the membership of the UK Catalysis Hub Consortium and funded by EPSRC grant: EP/R027129/1. We gratefully acknowledge supercomputer resources via the MCC/Archer HPC consortium (EP/R029431/1). ",

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AU - Mokhtar, Muhamad Z.

AU - Altujjar, Amal

AU - Wang, Bing

AU - Chen, Qian

AU - Ke, Jack Chun Ren

AU - Cai, Rongsheng

AU - Zibouche, Nourdine

AU - Spencer, Ben F.

AU - Jacobs, Janet

AU - Thomas, Andrew G.

AU - Hall, David

AU - Haigh, Sarah J.

AU - Lewis, David J.

AU - Curry, Richard

AU - Islam, M. Saiful

AU - Saunders, Brian R.

N1 - Funding Information: We would like to thank the EPSRC for funding (EP/R020590/1). This work including TEM access was supported by the Henry Royce Institute for Advanced Materials, funded through EPSRC grants EP/R00661X/1, EP/S019367/1, EP/P025021/1 and EP/P025498/1. S.J.H. acknowledges the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (Grant ERC-2016-STG-EvoluTEM-715502). R.C. and S.J.H. would like to thank the UK Catalysis Hub for resources and support provided via the membership of the UK Catalysis Hub Consortium and funded by EPSRC grant: EP/R027129/1. We gratefully acknowledge supercomputer resources via the MCC/Archer HPC consortium (EP/R029431/1).

PY - 2022/10/9

Y1 - 2022/10/9

N2 - Perovskite solar cells continue to attract interest due to their facile preparation and high power conversion efficiencies. However, the highest efficiency perovskite solar cells inevitably contain lead, which raises concerns over contamination of drinking water when a solar module is broken and then flooded. We previously showed that conventional synthetic hydroxyapatite (HAP) nanoparticles could capture some of the lead from broken solar cells, but the amount of lead released was well above the safe drinking water level. Here, we modify the HAP synthesis to prepare new spherical-HAP (s-HAP) nanoparticles with a 60% increase in the Pb absorption capacity. We blend s-HAPs with TiO2 nanoparticles to construct mixed scaffolds and investigate their effect on (FAPbI3)0.97(MAPbBr3)0.03 solar cell performance and lead capture. Replacement of 80% of the TiO2 nanoparticles with s-HAP causes the power conversion efficiency to increase from 18.61% to 20.32% as a result of decreased charge carrier recombination. Lead contamination of water from devices subjected to simulated hail damage followed by flooding is shown to decrease exponentially with increasing s-HAP content. The lead concentration in water after 24 h is below the US safe water drinking limit.

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ER -

Spherical hydroxyapatite nanoparticle scaffolds for reduced lead release from damaged perovskite solar cells

Abstract

Bibliographical note

ASJC Scopus subject areas

UN SDGs

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Spherical hydroxyapatite nanoparticle scaffolds for reduced lead release from damaged perovskite solar cells

Abstract

Bibliographical note

ASJC Scopus subject areas

UN SDGs

Access to Document

Other files and links

Fingerprint

Projects

AP19: Developing Catalyst Strategies for a Truly Circular Plastic Economy

Cite this