Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes

Richard G. Compton; Frank Marken; Thomas O. Rebbitt

doi:10.1039/cc9960001017

Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes

Richard G. Compton, Frank Marken, Thomas O. Rebbitt

University of Oxford

Research output: Contribution to journal › Article › peer-review

45 Citations (SciVal)

Abstract

Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer fast mass-transport properties so giving the electrodes the kinetic timescale of microelectrodes.

Original language	English
Pages (from-to)	1017-1018
Number of pages	2
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/cc9960001017
Publication status	Published - 1 Jan 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/cc9960001017

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title = "Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes",

abstract = "Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer fast mass-transport properties so giving the electrodes the kinetic timescale of microelectrodes.",

author = "Compton, \{Richard G.\} and Frank Marken and Rebbitt, \{Thomas O.\}",

year = "1996",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T2 - Making macroelectrodes behave like microelectrodes

AU - Compton, Richard G.

AU - Marken, Frank

AU - Rebbitt, Thomas O.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer fast mass-transport properties so giving the electrodes the kinetic timescale of microelectrodes.

AB - Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer fast mass-transport properties so giving the electrodes the kinetic timescale of microelectrodes.

UR - https://www.scopus.com/pages/publications/0001874334

U2 - 10.1039/cc9960001017

DO - 10.1039/cc9960001017

M3 - Article

AN - SCOPUS:0001874334

SN - 1359-7345

SP - 1017

EP - 1018

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes

Abstract

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