Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes

Richard G. Compton; Frank Marken; Thomas O. Rebbitt

doi:10.1039/cc9960001017

Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes

Richard G. Compton, Frank Marken, Thomas O. Rebbitt

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41 Citations (SciVal)

Abstract

Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer fast mass-transport properties so giving the electrodes the kinetic timescale of microelectrodes.

Original language	English
Pages (from-to)	1017-1018
Number of pages	2
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/cc9960001017
Publication status	Published - 1 Jan 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/cc9960001017

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title = "Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes",

abstract = "Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer fast mass-transport properties so giving the electrodes the kinetic timescale of microelectrodes.",

author = "Compton, {Richard G.} and Frank Marken and Rebbitt, {Thomas O.}",

year = "1996",

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T2 - Making macroelectrodes behave like microelectrodes

AU - Compton, Richard G.

AU - Marken, Frank

AU - Rebbitt, Thomas O.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer fast mass-transport properties so giving the electrodes the kinetic timescale of microelectrodes.

AB - Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer fast mass-transport properties so giving the electrodes the kinetic timescale of microelectrodes.

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JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

IS - 9

ER -

Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes

Abstract

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