Sonochemical acceleration of persulfate decomposition

Gareth J. Price, Andrew A. Clifton

Research output: Contribution to journalArticle

62 Citations (Scopus)

Abstract

The decomposition kinetics of potassium persulfate in aqueous solution have been investigated using a radical trapping method. The use of ultrasound was found to markedly accelerate the decomposition so that the sonochemical process at 25°C occurs at the same rate as the purely thermal reaction at 55°C. The effect of ultrasound intensity has also been studied and can be used to control the rate of decomposition within certain limits.

Original languageEnglish
Pages (from-to)3971-3973
Number of pages3
JournalPolymer
Volume37
Issue number17
DOIs
Publication statusPublished - Aug 1996

Keywords

  • Persulfate
  • Radical initiation
  • Sonochemistry

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics

Cite this