Some tricyclohexyltin carboxylates containing germanium: synthesis, spectral and crystallographic characterization

Din Imtiaz ud; K C Molloy; M Mazhar; S Dastgir; S Ali; M F Mahon

doi:10.1002/aoc.504

Some tricyclohexyltin carboxylates containing germanium: synthesis, spectral and crystallographic characterization

Din Imtiaz ud
, K C Molloy
, M Mazhar
, S Dastgir
, S Ali
, M F Mahon

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

37 Citations (SciVal)

Abstract

Six tricyclohexyltin triorganogermyl (substituted) propionates have been synthesized and their structures characterized by IR, multinuclear magnetic resonance (H-1, C-13, Sn-119) and Mossbauer spectroscopies. Three of them have been characterized crystallographically by X-ray diffraction. The crystal structures of [(p-CH3C6H4)(3)GeCH(p-CH3C6H4)CH2COOSn(C6H11)(3)] (1) and [(C6H5)(3)GeCH(C6H5)CH(CH3)COOSn(C6H11)(3)] (3) indicate that the tin possesses a tetrahedral geometry. The crystal structure of [(p-CH3C6H4)(3)GeCH(p-CH3OC6H4)CH2COOSn(C6H11)(3)]H2O (2) shows trigonal bipyramidal geometry around the tin with water of hydration enhancing the coordination sphere of the metal. Some of these compounds demonstrated positive antibacterial, antifungal and lethality bioassays. Copyright (C) 2003 John Wiley Sons, Ltd.

Original language	English
Pages (from-to)	781-787
Number of pages	7
Journal	Applied Organometallic Chemistry
Volume	17
Issue number	10
DOIs	https://doi.org/10.1002/aoc.504
Publication status	Published - 2003

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ID number: ISI:000185705000005

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@article{cafd0ea9d13241b593922c1cf2b5cbbd,

title = "Some tricyclohexyltin carboxylates containing germanium: synthesis, spectral and crystallographic characterization",

abstract = "Six tricyclohexyltin triorganogermyl (substituted) propionates have been synthesized and their structures characterized by IR, multinuclear magnetic resonance (H-1, C-13, Sn-119) and Mossbauer spectroscopies. Three of them have been characterized crystallographically by X-ray diffraction. The crystal structures of [(p-CH3C6H4)(3)GeCH(p-CH3C6H4)CH2COOSn(C6H11)(3)] (1) and [(C6H5)(3)GeCH(C6H5)CH(CH3)COOSn(C6H11)(3)] (3) indicate that the tin possesses a tetrahedral geometry. The crystal structure of [(p-CH3C6H4)(3)GeCH(p-CH3OC6H4)CH2COOSn(C6H11)(3)]H2O (2) shows trigonal bipyramidal geometry around the tin with water of hydration enhancing the coordination sphere of the metal. Some of these compounds demonstrated positive antibacterial, antifungal and lethality bioassays. Copyright (C) 2003 John Wiley Sons, Ltd.",

author = "\{Imtiaz ud\}, Din and Molloy, \{K C\} and M Mazhar and S Dastgir and S Ali and Mahon, \{M F\}",

note = "ID number: ISI:000185705000005",

year = "2003",

doi = "10.1002/aoc.504",

language = "English",

volume = "17",

pages = "781--787",

journal = "Applied Organometallic Chemistry",

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TY - JOUR

T1 - Some tricyclohexyltin carboxylates containing germanium: synthesis, spectral and crystallographic characterization

AU - Imtiaz ud, Din

AU - Molloy, K C

AU - Mazhar, M

AU - Dastgir, S

AU - Ali, S

AU - Mahon, M F

N1 - ID number: ISI:000185705000005

PY - 2003

Y1 - 2003

N2 - Six tricyclohexyltin triorganogermyl (substituted) propionates have been synthesized and their structures characterized by IR, multinuclear magnetic resonance (H-1, C-13, Sn-119) and Mossbauer spectroscopies. Three of them have been characterized crystallographically by X-ray diffraction. The crystal structures of [(p-CH3C6H4)(3)GeCH(p-CH3C6H4)CH2COOSn(C6H11)(3)] (1) and [(C6H5)(3)GeCH(C6H5)CH(CH3)COOSn(C6H11)(3)] (3) indicate that the tin possesses a tetrahedral geometry. The crystal structure of [(p-CH3C6H4)(3)GeCH(p-CH3OC6H4)CH2COOSn(C6H11)(3)]H2O (2) shows trigonal bipyramidal geometry around the tin with water of hydration enhancing the coordination sphere of the metal. Some of these compounds demonstrated positive antibacterial, antifungal and lethality bioassays. Copyright (C) 2003 John Wiley Sons, Ltd.

AB - Six tricyclohexyltin triorganogermyl (substituted) propionates have been synthesized and their structures characterized by IR, multinuclear magnetic resonance (H-1, C-13, Sn-119) and Mossbauer spectroscopies. Three of them have been characterized crystallographically by X-ray diffraction. The crystal structures of [(p-CH3C6H4)(3)GeCH(p-CH3C6H4)CH2COOSn(C6H11)(3)] (1) and [(C6H5)(3)GeCH(C6H5)CH(CH3)COOSn(C6H11)(3)] (3) indicate that the tin possesses a tetrahedral geometry. The crystal structure of [(p-CH3C6H4)(3)GeCH(p-CH3OC6H4)CH2COOSn(C6H11)(3)]H2O (2) shows trigonal bipyramidal geometry around the tin with water of hydration enhancing the coordination sphere of the metal. Some of these compounds demonstrated positive antibacterial, antifungal and lethality bioassays. Copyright (C) 2003 John Wiley Sons, Ltd.

U2 - 10.1002/aoc.504

DO - 10.1002/aoc.504

M3 - Article

SN - 0268-2605

VL - 17

SP - 781

EP - 787

JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 10

ER -

Some tricyclohexyltin carboxylates containing germanium: synthesis, spectral and crystallographic characterization

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