Some triarylgermyl substituted chiral triphenyltin derivatives: Their synthesis, characterization and X-ray crystal structure

Din Imtiaz ud, M Mazhar, K C Molloy

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Some chiral triphenyltin complexes (1-4) derived from triarylgermyl(substituted)-propenoic acids (I-D) have been prepared. They were characterized by IR, mass spectrometry and multinuclear (H-1, C-13, Sn-119) NMR spectroscopic techniques and their chirality was established on the basis of H-1 NMR data and specific rotation values. X-Ray structure of the synthesized ligand, I-D3, (m-CH3C6H4)(3)GeCH(C6H5)CH2COOH, depicts chiral and prochiral carbons explicitly and described tetrahedral geometry around the germanium atom.
Original languageEnglish
Pages (from-to)11-19
Number of pages9
JournalMain Group Metal Chemistry
Volume29
Issue number1
Publication statusPublished - 2006

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