Abstract
Some chiral triphenyltin complexes (1-4) derived from triarylgermyl(substituted)-propenoic acids (I-D) have been prepared. They were characterized by IR, mass spectrometry and multinuclear (H-1, C-13, Sn-119) NMR spectroscopic techniques and their chirality was established on the basis of H-1 NMR data and specific rotation values. X-Ray structure of the synthesized ligand, I-D3, (m-CH3C6H4)(3)GeCH(C6H5)CH2COOH, depicts chiral and prochiral carbons explicitly and described tetrahedral geometry around the germanium atom.
Original language | English |
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Pages (from-to) | 11-19 |
Number of pages | 9 |
Journal | Main Group Metal Chemistry |
Volume | 29 |
Issue number | 1 |
Publication status | Published - 2006 |