TY - JOUR
T1 - Solvothermal synthesis of chromium(III) complexes with the 'Bis-tris' ligand
AU - Graham, K.
AU - Sharp, L.E.
AU - Murrie, M.
AU - Thomas, L.H.
PY - 2012/11
Y1 - 2012/11
N2 - In methanol under solvothermal conditions, we show how the nuclearity of the complex can be tuned from a monomer [Cr III(H 3L)Cl] (1) to a tetramer [Cr III 4(H 2L) 4] (2) with an unusual twisted {M 4O 4} core topology {Bis-tris, H 5L = (HOCH 2CH 2) 2NC(CH 2OH) 3}. The magnetic data for 2 can be fitted to a simple 1J model with J = - 20.25(5) cm - 1
AB - In methanol under solvothermal conditions, we show how the nuclearity of the complex can be tuned from a monomer [Cr III(H 3L)Cl] (1) to a tetramer [Cr III 4(H 2L) 4] (2) with an unusual twisted {M 4O 4} core topology {Bis-tris, H 5L = (HOCH 2CH 2) 2NC(CH 2OH) 3}. The magnetic data for 2 can be fitted to a simple 1J model with J = - 20.25(5) cm - 1
UR - http://www.scopus.com/inward/record.url?scp=84867492188&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1016/j.inoche.2012.08.024
U2 - 10.1016/j.inoche.2012.08.024
DO - 10.1016/j.inoche.2012.08.024
M3 - Article
AN - SCOPUS:84867492188
SN - 1387-7003
VL - 25
SP - 89
EP - 91
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -