Solvent hydrolysis and templating effects in the synthesis of metal-organic frameworks

Andrew Burrows; Kevin Cassar; Richard M. W. Friend; Mary F. Mahon; Sean P Rigby; John E. Warren

doi:10.1039/b509460g

Solvent hydrolysis and templating effects in the synthesis of metal-organic frameworks

Andrew Burrows, Kevin Cassar, Richard M. W. Friend, Mary F. Mahon, Sean P Rigby, John E. Warren

Research output: Contribution to journal › Article › peer-review

255 Citations (SciVal)

Abstract

Hydrolysis of the DMF or DEF solvent influences the nature of the product obsd. in the reaction between Zn(II) nitrate and 1,4-benzenedicarboxylic acid, with dialkylammonium cations able to template the formation of anionic networks. In fresh DEF [Zn4(micro 4-O)(micro -bdc)3].3DEF was prepd. whereas in DEF that had been in the lab. for several weeks, [NH2Et2]2[Zn3(micro -bdc)4].2.5DEF was prepd. When the reactions were carried out in DMF instead of DEF, similar observations were recorded. Use of a partially hydrolyzed sample of solvent, or addn. of [NH2Me2]Cl. led exclusively to [NH2Me2]2[Zn3(micro -bdc)4].DMF.H2O. The prepn. and characterization of compds. 1-3 demonstrate that solvent quality is crucially important in prepg. dicarboxylate-based coordination compds. [on SciFinder (R)]

Original language	English
Pages (from-to)	548-550
Number of pages	3
Journal	CrystEngComm
Volume	7
Issue number	89
Early online date	12 Aug 2005
DOIs	https://doi.org/10.1039/b509460g
Publication status	Published - 2005

Bibliographical note

ID number: ISI:000231712800001

Keywords

zinc benzenedicarboxylate trinuclear tetranuclear complex prepn unhydrolyzed hydrolyzed solvent
Molecular structure (of zinc benzenedicarboxylate trinuclear complex ethylammonium salt)
Hydrolysis (of DMF or diethylformamide solvent in the reaction between zinc nitrate and benzenedicarboxylic acid)
crystal structure zinc benzenedicarboxylate trinuclear complex ethylammonium salt
Crystal structure

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@article{0958d9b794674cebab98221a94bb5483,

title = "Solvent hydrolysis and templating effects in the synthesis of metal-organic frameworks",

abstract = "Hydrolysis of the DMF or DEF solvent influences the nature of the product obsd. in the reaction between Zn(II) nitrate and 1,4-benzenedicarboxylic acid, with dialkylammonium cations able to template the formation of anionic networks. In fresh DEF [Zn4(micro 4-O)(micro -bdc)3].3DEF was prepd. whereas in DEF that had been in the lab. for several weeks, [NH2Et2]2[Zn3(micro -bdc)4].2.5DEF was prepd. When the reactions were carried out in DMF instead of DEF, similar observations were recorded. Use of a partially hydrolyzed sample of solvent, or addn. of [NH2Me2]Cl. led exclusively to [NH2Me2]2[Zn3(micro -bdc)4].DMF.H2O. The prepn. and characterization of compds. 1-3 demonstrate that solvent quality is crucially important in prepg. dicarboxylate-based coordination compds. [on SciFinder (R)]",

keywords = "zinc benzenedicarboxylate trinuclear tetranuclear complex prepn unhydrolyzed hydrolyzed solvent, Molecular structure (of zinc benzenedicarboxylate trinuclear complex ethylammonium salt), Hydrolysis (of DMF or diethylformamide solvent in the reaction between zinc nitrate and benzenedicarboxylic acid), crystal structure zinc benzenedicarboxylate trinuclear complex ethylammonium salt, Crystal structure",

author = "Andrew Burrows and Kevin Cassar and Friend, {Richard M. W.} and Mahon, {Mary F.} and Rigby, {Sean P} and Warren, {John E.}",

note = "ID number: ISI:000231712800001",

year = "2005",

doi = "10.1039/b509460g",

language = "English",

volume = "7",

pages = "548--550",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "89",

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TY - JOUR

T1 - Solvent hydrolysis and templating effects in the synthesis of metal-organic frameworks

AU - Burrows, Andrew

AU - Cassar, Kevin

AU - Friend, Richard M. W.

AU - Mahon, Mary F.

AU - Rigby, Sean P

AU - Warren, John E.

N1 - ID number: ISI:000231712800001

PY - 2005

Y1 - 2005

N2 - Hydrolysis of the DMF or DEF solvent influences the nature of the product obsd. in the reaction between Zn(II) nitrate and 1,4-benzenedicarboxylic acid, with dialkylammonium cations able to template the formation of anionic networks. In fresh DEF [Zn4(micro 4-O)(micro -bdc)3].3DEF was prepd. whereas in DEF that had been in the lab. for several weeks, [NH2Et2]2[Zn3(micro -bdc)4].2.5DEF was prepd. When the reactions were carried out in DMF instead of DEF, similar observations were recorded. Use of a partially hydrolyzed sample of solvent, or addn. of [NH2Me2]Cl. led exclusively to [NH2Me2]2[Zn3(micro -bdc)4].DMF.H2O. The prepn. and characterization of compds. 1-3 demonstrate that solvent quality is crucially important in prepg. dicarboxylate-based coordination compds. [on SciFinder (R)]

AB - Hydrolysis of the DMF or DEF solvent influences the nature of the product obsd. in the reaction between Zn(II) nitrate and 1,4-benzenedicarboxylic acid, with dialkylammonium cations able to template the formation of anionic networks. In fresh DEF [Zn4(micro 4-O)(micro -bdc)3].3DEF was prepd. whereas in DEF that had been in the lab. for several weeks, [NH2Et2]2[Zn3(micro -bdc)4].2.5DEF was prepd. When the reactions were carried out in DMF instead of DEF, similar observations were recorded. Use of a partially hydrolyzed sample of solvent, or addn. of [NH2Me2]Cl. led exclusively to [NH2Me2]2[Zn3(micro -bdc)4].DMF.H2O. The prepn. and characterization of compds. 1-3 demonstrate that solvent quality is crucially important in prepg. dicarboxylate-based coordination compds. [on SciFinder (R)]

KW - zinc benzenedicarboxylate trinuclear tetranuclear complex prepn unhydrolyzed hydrolyzed solvent

KW - Molecular structure (of zinc benzenedicarboxylate trinuclear complex ethylammonium salt)

KW - Hydrolysis (of DMF or diethylformamide solvent in the reaction between zinc nitrate and benzenedicarboxylic acid)

KW - crystal structure zinc benzenedicarboxylate trinuclear complex ethylammonium salt

KW - Crystal structure

UR - http://dx.doi.org/10.1039/b509460g

U2 - 10.1039/b509460g

DO - 10.1039/b509460g

M3 - Article

SN - 1466-8033

VL - 7

SP - 548

EP - 550

JO - CrystEngComm

JF - CrystEngComm

IS - 89

ER -

Solvent hydrolysis and templating effects in the synthesis of metal-organic frameworks

Abstract

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Keywords

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