TY - JOUR
T1 - Solvent-free processing of lignin into robust room temperature phosphorescent materials
AU - Wang, Min
AU - Yin, Wei Ming
AU - Zhai, Yingxiang
AU - Zhou, Jingyi
AU - Liu, Shouxin
AU - Li, Jian
AU - Li, Shujun
AU - Chen, Zhijun
AU - James, Tony
PY - 2025/3/12
Y1 - 2025/3/12
N2 - Producing room temperature phosphorescent (RTP) materials from biomass resources using a solvent free method is essential but hard to achieve. Here, we discovered that lignin dissolved well in the liquid monomer, 2-hydroxyethyl acrylate (HEA), due to extensive hydrogen bonding and non-bonding interactions between lignin and HEA. Motivated by this discovery, we developed a solvent free system consisting of HEA and urethane dimethacrylate (UDMA) for converting lignin into RTP materials. With this design, lignin generated radicals upon UV irradiation, which initiated the polymerization of HEA (as monomer) and UDMA (as crosslinker). The as-obtained polymer network rigidifies lignin and activates the humidity/water-resistant RTP of lignin with a lifetime of 202.9 ms. Moreover, the afterglow color was successfully tuned to red after loading with RhB via energy transfer (TS-FRET). Using these properties, the as-developed material was used as photocured multiple-emission RTP inks, luminescent coatings and a smart anti-counterfeiting logo for a medicine bottle.
AB - Producing room temperature phosphorescent (RTP) materials from biomass resources using a solvent free method is essential but hard to achieve. Here, we discovered that lignin dissolved well in the liquid monomer, 2-hydroxyethyl acrylate (HEA), due to extensive hydrogen bonding and non-bonding interactions between lignin and HEA. Motivated by this discovery, we developed a solvent free system consisting of HEA and urethane dimethacrylate (UDMA) for converting lignin into RTP materials. With this design, lignin generated radicals upon UV irradiation, which initiated the polymerization of HEA (as monomer) and UDMA (as crosslinker). The as-obtained polymer network rigidifies lignin and activates the humidity/water-resistant RTP of lignin with a lifetime of 202.9 ms. Moreover, the afterglow color was successfully tuned to red after loading with RhB via energy transfer (TS-FRET). Using these properties, the as-developed material was used as photocured multiple-emission RTP inks, luminescent coatings and a smart anti-counterfeiting logo for a medicine bottle.
U2 - 10.1038/s41467-025-57712-x
DO - 10.1038/s41467-025-57712-x
M3 - Article
SN - 2041-1723
JO - Nature Communications
JF - Nature Communications
M1 - 2455
ER -