Solvent directed aggregation of a metallocene; structures of {[Pb(η-C5H5)2]3·C 6H5Me}∞ and [Pb(η-C5H5)2]6

Michael A. Beswick; Catherine Lopez-Casideo; Michael A. Paver; Paul R. Raithby; Christopher A. Russell; Alexander Steiner; Dominic S. Wright

doi:10.1039/a607561d

Solvent directed aggregation of a metallocene; structures of {[Pb(η-C₅H₅)₂]₃·C ₆H₅Me}_∞ and [Pb(η-C₅H₅)₂]₆

Michael A. Beswick
, Catherine Lopez-Casideo
, Michael A. Paver
, Paul R. Raithby
, Christopher A. Russell
, Alexander Steiner
, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

17 Citations (SciVal)

Abstract

The classic zigzagged chain structure of orthorhombic plumbocene, [Pb(η-C₅H₅)₂]_∞, is obtained by crystal growth from the vapour phase; however, crystallisation from toluene results in modification of the conformation of the polymer chain, as observed in the solvate [Pb(η-C₅H₅)·C₆H₅Me] _∞ 1, and cyclisation into hexamers, as seen in the new hexagonal phase [Pb(η-C₅H₅)₂]₆ 2.

Original language	English
Pages (from-to)	109-110
Number of pages	2
Journal	Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/a607561d
Publication status	Published - 1 Jan 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a607561d

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title = "Solvent directed aggregation of a metallocene; structures of \{[Pb(η-C5H5)2]3·C 6H5Me\}∞ and [Pb(η-C5H5)2]6",

abstract = "The classic zigzagged chain structure of orthorhombic plumbocene, [Pb(η-C5H5)2]∞, is obtained by crystal growth from the vapour phase; however, crystallisation from toluene results in modification of the conformation of the polymer chain, as observed in the solvate [Pb(η-C5H5)·C6H5Me] ∞ 1, and cyclisation into hexamers, as seen in the new hexagonal phase [Pb(η-C5H5)2]6 2.",

author = "Beswick, \{Michael A.\} and Catherine Lopez-Casideo and Paver, \{Michael A.\} and Raithby, \{Paul R.\} and Russell, \{Christopher A.\} and Alexander Steiner and Wright, \{Dominic S.\}",

year = "1997",

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doi = "10.1039/a607561d",

language = "English",

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journal = "Chemical Communications",

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T1 - Solvent directed aggregation of a metallocene; structures of {[Pb(η-C5H5)2]3·C 6H5Me}∞ and [Pb(η-C5H5)2]6

AU - Beswick, Michael A.

AU - Lopez-Casideo, Catherine

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Russell, Christopher A.

AU - Steiner, Alexander

AU - Wright, Dominic S.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The classic zigzagged chain structure of orthorhombic plumbocene, [Pb(η-C5H5)2]∞, is obtained by crystal growth from the vapour phase; however, crystallisation from toluene results in modification of the conformation of the polymer chain, as observed in the solvate [Pb(η-C5H5)·C6H5Me] ∞ 1, and cyclisation into hexamers, as seen in the new hexagonal phase [Pb(η-C5H5)2]6 2.

AB - The classic zigzagged chain structure of orthorhombic plumbocene, [Pb(η-C5H5)2]∞, is obtained by crystal growth from the vapour phase; however, crystallisation from toluene results in modification of the conformation of the polymer chain, as observed in the solvate [Pb(η-C5H5)·C6H5Me] ∞ 1, and cyclisation into hexamers, as seen in the new hexagonal phase [Pb(η-C5H5)2]6 2.

UR - https://www.scopus.com/pages/publications/0006948718

U2 - 10.1039/a607561d

DO - 10.1039/a607561d

M3 - Article

AN - SCOPUS:0006948718

SN - 1359-7345

SP - 109

EP - 110

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Solvent directed aggregation of a metallocene; structures of {[Pb(η-C₅H₅)₂]₃·C ₆H₅Me}_∞ and [Pb(η-C₅H₅)₂]₆

Abstract

ASJC Scopus subject areas

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