Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amidet

Anthony G. Avent, Mark R. Crimmin, Michael S. Hill, Peter B. Hitchcock

Research output: Contribution to journalArticlepeer-review

26 Citations (Scopus)

Abstract

'Selective' protonolysis of the β-diketiminato calcium derivative [Ca{(NDippCMe)2CH}{N(SiMe3)2}(THF)] (Dipp = C6H3iPr2-2,6) with H 2N(CH2)2OCH3 produced the dimeric species [Ca{(NDippCMe)2CH}{μ-NH(CH2) 2OMe}]2, which has been fully characterised in solution and in the solid state.

Original languageEnglish
Pages (from-to)3166-3168
Number of pages3
JournalDalton Transactions
Issue number20
DOIs
Publication statusPublished - 21 Oct 2004

ASJC Scopus subject areas

  • Inorganic Chemistry

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