Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amidet

Anthony G. Avent; Mark R. Crimmin; Michael S. Hill; Peter B. Hitchcock

doi:10.1039/b412060d

Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amidet

Anthony G. Avent, Mark R. Crimmin, Michael S. Hill, Peter B. Hitchcock

Research output: Contribution to journal › Article › peer-review

28 Citations (SciVal)

Abstract

'Selective' protonolysis of the β-diketiminato calcium derivative [Ca{(NDippCMe)₂CH}{N(SiMe₃)₂}(THF)] (Dipp = C₆H₃ⁱPr₂-2,6) with H ₂N(CH₂)₂OCH₃ produced the dimeric species [Ca{(NDippCMe)₂CH}{μ-NH(CH₂) ₂OMe}]₂, which has been fully characterised in solution and in the solid state.

Original language	English
Pages (from-to)	3166-3168
Number of pages	3
Journal	Dalton Transactions
Issue number	20
DOIs	https://doi.org/10.1039/b412060d
Publication status	Published - 21 Oct 2004

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amidet",

abstract = "'Selective' protonolysis of the β-diketiminato calcium derivative [Ca{(NDippCMe)2CH}{N(SiMe3)2}(THF)] (Dipp = C6H3iPr2-2,6) with H 2N(CH2)2OCH3 produced the dimeric species [Ca{(NDippCMe)2CH}{μ-NH(CH2) 2OMe}]2, which has been fully characterised in solution and in the solid state.",

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AU - Avent, Anthony G.

AU - Crimmin, Mark R.

AU - Hill, Michael S.

AU - Hitchcock, Peter B.

PY - 2004/10/21

Y1 - 2004/10/21

N2 - 'Selective' protonolysis of the β-diketiminato calcium derivative [Ca{(NDippCMe)2CH}{N(SiMe3)2}(THF)] (Dipp = C6H3iPr2-2,6) with H 2N(CH2)2OCH3 produced the dimeric species [Ca{(NDippCMe)2CH}{μ-NH(CH2) 2OMe}]2, which has been fully characterised in solution and in the solid state.

AB - 'Selective' protonolysis of the β-diketiminato calcium derivative [Ca{(NDippCMe)2CH}{N(SiMe3)2}(THF)] (Dipp = C6H3iPr2-2,6) with H 2N(CH2)2OCH3 produced the dimeric species [Ca{(NDippCMe)2CH}{μ-NH(CH2) 2OMe}]2, which has been fully characterised in solution and in the solid state.

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U2 - 10.1039/b412060d

DO - 10.1039/b412060d

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JF - Dalton Transactions

IS - 20

ER -

Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amidet

Abstract

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