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The reaction of silver(I) perchlorate with the semi-rigid ligand 1,4-bis((3,5-dimethylisoxazol-4-yl)methyl) benzene (bisox) in methanol gives a triply-interpenetrated sheet structure, but a structure containing both interpenetrated sheets and Ag-2(bisox)(3) cages is formed on recrystallisation from acetonitrile-diethyl ether. Rearrangement of the cages into sheets occurs on heating under vacuum, a process which involves a solid state change in conformation of the bisox ligands.
|Number of pages||3|
|Publication status||Published - 28 Jul 2010|
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- 1 Finished
A NEW TYPE OF HETEROGENEOUS CATALYST FOR PROCESSES INVOLVING HYDROGENATIONS
Engineering and Physical Sciences Research Council
14/11/05 → 13/02/08
Project: Research council