Solid- and solution-state structures of indium 'alkene analogues'

Michael S. Hill; Peter B. Hitchcock; Ruti Pongtavornpinyo

doi:10.1039/b616747k

Solid- and solution-state structures of indium 'alkene analogues'

Michael S. Hill
, Peter B. Hitchcock
, Ruti Pongtavornpinyo

Imperial College London
University of Sussex

Research output: Contribution to journal › Article › peer-review

27 Citations (SciVal)

Abstract

Although the nuclearity of In(i) ‘carbenes’ is dependent upon the steric demands of the supporting β-diketiminate ligand, it is shown by solution NMR diffusion (DOSY) methods that the In–In interactions observed in the solid-state are very weak and not retained in solution.

Original language	English
Pages (from-to)	731-733
Number of pages	3
Journal	Dalton Transactions
Volume	2007
Issue number	7
Early online date	29 Nov 2006
DOIs	https://doi.org/10.1039/b616747k
Publication status	Published - 13 Feb 2007

ASJC Scopus subject areas

Inorganic Chemistry

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abstract = "Although the nuclearity of In(i) {\textquoteleft}carbenes{\textquoteright} is dependent upon the steric demands of the supporting β-diketiminate ligand, it is shown by solution NMR diffusion (DOSY) methods that the In–In interactions observed in the solid-state are very weak and not retained in solution.",

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AU - Hill, Michael S.

AU - Hitchcock, Peter B.

AU - Pongtavornpinyo, Ruti

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N2 - Although the nuclearity of In(i) ‘carbenes’ is dependent upon the steric demands of the supporting β-diketiminate ligand, it is shown by solution NMR diffusion (DOSY) methods that the In–In interactions observed in the solid-state are very weak and not retained in solution.

AB - Although the nuclearity of In(i) ‘carbenes’ is dependent upon the steric demands of the supporting β-diketiminate ligand, it is shown by solution NMR diffusion (DOSY) methods that the In–In interactions observed in the solid-state are very weak and not retained in solution.

UR - https://www.scopus.com/pages/publications/33846881569

U2 - 10.1039/b616747k

DO - 10.1039/b616747k

M3 - Article

AN - SCOPUS:33846881569

SN - 1477-9226

VL - 2007

SP - 731

EP - 733

JO - Dalton Transactions

JF - Dalton Transactions

IS - 7

ER -

Solid- and solution-state structures of indium 'alkene analogues'

Abstract

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