Sodium Trihydrogen-1,4-Benzenediphosphonate: An Extended Coordination Network

A A Ayi; Andrew D Burrows; Mary F Mahon; Viorica M Pop

doi:10.1007/s10870-011-0064-0

Sodium Trihydrogen-1,4-Benzenediphosphonate: An Extended Coordination Network

A A Ayi, Andrew D Burrows, Mary F Mahon, Viorica M Pop

Department of Chemistry

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Abstract

Crystals of sodium trihydrogen-1,4-benzenediphosphonate, Na[H(3)bdp], were prepared from the addition of aqueous sodium hydroxide to an acidified solution of 1,4-benzenediphosphonic acid (H(4)bdp). These were shown by X-ray crystallography to crystallize in the space group P (1) over bar, with cell parameters a = 5.7500(3) , b = 7.9180(5) , c = 10.4420(6) , alpha = 80.398(3)A degrees, beta A = 76.844(4)A degrees and gamma A = 81.389(4)A degrees. The crystal structure revealed that the title compound forms a coordination network in which sodium-phosphonate sheets are pillared by the benzene rings into a three-dimensional structure.

Original language	English
Pages (from-to)	1165-1168
Number of pages	4
Journal	Journal of Chemical Crystallography
Volume	41
Issue number	8
DOIs	https://doi.org/10.1007/s10870-011-0064-0
Publication status	Published - Aug 2011

Keywords

sodium salts
coordination networks
phosphonates
coordination polymers

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Burrows_JCC_2011_41_8_1165.pdf
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Cite this

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title = "Sodium Trihydrogen-1,4-Benzenediphosphonate: An Extended Coordination Network",

abstract = "Crystals of sodium trihydrogen-1,4-benzenediphosphonate, Na[H(3)bdp], were prepared from the addition of aqueous sodium hydroxide to an acidified solution of 1,4-benzenediphosphonic acid (H(4)bdp). These were shown by X-ray crystallography to crystallize in the space group P (1) over bar, with cell parameters a = 5.7500(3) , b = 7.9180(5) , c = 10.4420(6) , alpha = 80.398(3)A degrees, beta A = 76.844(4)A degrees and gamma A = 81.389(4)A degrees. The crystal structure revealed that the title compound forms a coordination network in which sodium-phosphonate sheets are pillared by the benzene rings into a three-dimensional structure.",

keywords = "sodium salts, coordination networks, phosphonates, coordination polymers",

author = "Ayi, {A A} and Burrows, {Andrew D} and Mahon, {Mary F} and Pop, {Viorica M}",

year = "2011",

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doi = "10.1007/s10870-011-0064-0",

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T1 - Sodium Trihydrogen-1,4-Benzenediphosphonate: An Extended Coordination Network

AU - Ayi, A A

AU - Burrows, Andrew D

AU - Mahon, Mary F

AU - Pop, Viorica M

PY - 2011/8

Y1 - 2011/8

N2 - Crystals of sodium trihydrogen-1,4-benzenediphosphonate, Na[H(3)bdp], were prepared from the addition of aqueous sodium hydroxide to an acidified solution of 1,4-benzenediphosphonic acid (H(4)bdp). These were shown by X-ray crystallography to crystallize in the space group P (1) over bar, with cell parameters a = 5.7500(3) , b = 7.9180(5) , c = 10.4420(6) , alpha = 80.398(3)A degrees, beta A = 76.844(4)A degrees and gamma A = 81.389(4)A degrees. The crystal structure revealed that the title compound forms a coordination network in which sodium-phosphonate sheets are pillared by the benzene rings into a three-dimensional structure.

AB - Crystals of sodium trihydrogen-1,4-benzenediphosphonate, Na[H(3)bdp], were prepared from the addition of aqueous sodium hydroxide to an acidified solution of 1,4-benzenediphosphonic acid (H(4)bdp). These were shown by X-ray crystallography to crystallize in the space group P (1) over bar, with cell parameters a = 5.7500(3) , b = 7.9180(5) , c = 10.4420(6) , alpha = 80.398(3)A degrees, beta A = 76.844(4)A degrees and gamma A = 81.389(4)A degrees. The crystal structure revealed that the title compound forms a coordination network in which sodium-phosphonate sheets are pillared by the benzene rings into a three-dimensional structure.

KW - sodium salts

KW - coordination networks

KW - phosphonates

KW - coordination polymers

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DO - 10.1007/s10870-011-0064-0

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JO - Journal of Chemical Crystallography

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Sodium Trihydrogen-1,4-Benzenediphosphonate: An Extended Coordination Network

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Keywords

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Sodium Trihydrogen-1,4-Benzenediphosphonate: An Extended Coordination Network

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