Skeletal characterisation of high nuclearity osmium carbonyl clusters by extended x-ray absorption fine structure (EXAFS) spectroscopy

Stephen L. Cook, John Evans, G. Neville Greaves, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Peter B. Wells, Peter Worthington

Research output: Contribution to journalArticlepeer-review

Abstract

Non-bonded osmium-osmium distances have been identified from the EXAFS of the Os L(III) edge spectra of Os6(CO)18. [N(PPh 3)2]2[Os6(CO)18], and [N(PPh3)2]2[Os10C(CO)24] and can be used to characterise the cluster skeleton.

Original languageEnglish
Pages (from-to)777-779
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number14
DOIs
Publication statusPublished - 1983

ASJC Scopus subject areas

  • Molecular Medicine

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