Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO2 over N2

D M Jiang; Andrew D Burrows; Karen J Edler

doi:10.1039/c1ce06274c

Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO₂ over N₂

D M Jiang
, Andrew D Burrows
, Karen J Edler

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

158 Citations (SciVal)

629 Downloads (Pure)

Abstract

Nanoparticles of MIL-101(Cr) have been fabricated using a hydrothermal method for the first time. The particle size can be controlled from 19 (4) nm to 84 (12) nm, by using a monocarboxylic acid as a mediator. These nano MIL-101(Cr) materials exhibit higher selectivities for CO(2) over N(2) than bulk MIL-101(Cr).

Original language	English
Pages (from-to)	6916-6919
Number of pages	4
Journal	CrystEngComm
Volume	13
Issue number	23
DOIs	https://doi.org/10.1039/c1ce06274c
Publication status	Published - 2011

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10.1039/c1ce06274c

Author's accepted versionAccepted author manuscript, 6.97 MB

Cite this

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title = "Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO2 over N2",

abstract = "Nanoparticles of MIL-101(Cr) have been fabricated using a hydrothermal method for the first time. The particle size can be controlled from 19 (4) nm to 84 (12) nm, by using a monocarboxylic acid as a mediator. These nano MIL-101(Cr) materials exhibit higher selectivities for CO(2) over N(2) than bulk MIL-101(Cr).",

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AU - Jiang, D M

AU - Burrows, Andrew D

AU - Edler, Karen J

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N2 - Nanoparticles of MIL-101(Cr) have been fabricated using a hydrothermal method for the first time. The particle size can be controlled from 19 (4) nm to 84 (12) nm, by using a monocarboxylic acid as a mediator. These nano MIL-101(Cr) materials exhibit higher selectivities for CO(2) over N(2) than bulk MIL-101(Cr).

AB - Nanoparticles of MIL-101(Cr) have been fabricated using a hydrothermal method for the first time. The particle size can be controlled from 19 (4) nm to 84 (12) nm, by using a monocarboxylic acid as a mediator. These nano MIL-101(Cr) materials exhibit higher selectivities for CO(2) over N(2) than bulk MIL-101(Cr).

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UR - http://dx.doi.org/10.1039/c1ce06274c

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DO - 10.1039/c1ce06274c

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JO - CrystEngComm

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Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO₂ over N₂

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Nano-Integration of Metal-Organic Frameworks and Catalysis for the Uptake and Utilisation of CO2

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Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO2 over N2

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Nano-Integration of Metal-Organic Frameworks and Catalysis for the Uptake and Utilisation of CO2

Cite this

Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO₂ over N₂