Site selectivity in the reactions of nucleophiles with [Ru5C(CO)15]: X-ray analysis of [Ru5C(CO)14(µ-η2-MeCO)(AuPPh3)] and [Ru5C(CO)13(η5-C5H5)(AuPPh3)], the first high nuclearity cyclopentadienylruthenium cluster

Alan G. Cowie; Brian F.G. Johnson; Jack Lewis; J. Nicola Nicholls; Paul R. Raithby; Alistair G. Swanson

doi:10.1039/C39840000637

Site selectivity in the reactions of nucleophiles with [Ru₅C(CO)₁₅]: X-ray analysis of [Ru₅C(CO)₁₄(µ-η²-MeCO)(AuPPh₃)] and [Ru₅C(CO)₁₃(η⁵-C₅H₅)(AuPPh₃)], the first high nuclearity cyclopentadienylruthenium cluster

Alan G. Cowie, Brian F.G. Johnson, Jack Lewis, J. Nicola Nicholls, Paul R. Raithby, Alistair G. Swanson

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The cluster [Ru₅C(CO)₁₅] reacts with LiMe, followed by [Ph₃PAu][Cl], to give [Ru₅C(CO)₁₄(µ-η²-MeCO)(AuPPh₃)] while reaction with NaC₅H₅, followed by [Ph₃PAu][ClO₄], gives [Ru₅C(CO)₁₃(η⁵-C₅H₅)(AuPPh₃)]; X-ray analysis has confirmed that the nucleophile has attacked a carbonyl ligand in the former case but a metal centre in the latter.

Original language	English
Pages (from-to)	637-639
Number of pages	3
Journal	Journal of the Chemical Society - Series Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39840000637
Publication status	Published - 31 Dec 1984

ASJC Scopus subject areas

Molecular Medicine

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Cowie, A. G., Johnson, B. F. G., Lewis, J., Nicholls, J. N., Raithby, P. R., & Swanson, A. G. (1984). Site selectivity in the reactions of nucleophiles with [Ru₅C(CO)₁₅]: X-ray analysis of [Ru₅C(CO)₁₄(µ-η²-MeCO)(AuPPh₃)] and [Ru₅C(CO)₁₃(η⁵-C₅H₅)(AuPPh₃)], the first high nuclearity cyclopentadienylruthenium cluster. Journal of the Chemical Society - Series Chemical Communications, (10), 637-639. https://doi.org/10.1039/C39840000637

Site selectivity in the reactions of nucleophiles with [Ru₅C(CO)₁₅]: X-ray analysis of [Ru₅C(CO)₁₄(µ-η²-MeCO)(AuPPh₃)] and [Ru₅C(CO)₁₃(η⁵-C₅H₅)(AuPPh₃)], the first high nuclearity cyclopentadienylruthenium cluster. / Cowie, Alan G.; Johnson, Brian F.G.; Lewis, Jack et al.
In: Journal of the Chemical Society - Series Chemical Communications, No. 10, 31.12.1984, p. 637-639.

Research output: Contribution to journal › Article › peer-review

Cowie, AG, Johnson, BFG, Lewis, J, Nicholls, JN, Raithby, PR & Swanson, AG 1984, 'Site selectivity in the reactions of nucleophiles with [Ru₅C(CO)₁₅]: X-ray analysis of [Ru₅C(CO)₁₄(µ-η²-MeCO)(AuPPh₃)] and [Ru₅C(CO)₁₃(η⁵-C₅H₅)(AuPPh₃)], the first high nuclearity cyclopentadienylruthenium cluster', Journal of the Chemical Society - Series Chemical Communications, no. 10, pp. 637-639. https://doi.org/10.1039/C39840000637

Cowie AG, Johnson BFG, Lewis J, Nicholls JN, Raithby PR, Swanson AG. Site selectivity in the reactions of nucleophiles with [Ru₅C(CO)₁₅]: X-ray analysis of [Ru₅C(CO)₁₄(µ-η²-MeCO)(AuPPh₃)] and [Ru₅C(CO)₁₃(η⁵-C₅H₅)(AuPPh₃)], the first high nuclearity cyclopentadienylruthenium cluster. Journal of the Chemical Society - Series Chemical Communications. 1984 Dec 31;(10):637-639. doi: 10.1039/C39840000637

Cowie, Alan G. ; Johnson, Brian F.G. ; Lewis, Jack et al. / Site selectivity in the reactions of nucleophiles with [Ru₅C(CO)₁₅] : X-ray analysis of [Ru₅C(CO)₁₄(µ-η²-MeCO)(AuPPh₃)] and [Ru₅C(CO)₁₃(η⁵-C₅H₅)(AuPPh₃)], the first high nuclearity cyclopentadienylruthenium cluster. In: Journal of the Chemical Society - Series Chemical Communications. 1984 ; No. 10. pp. 637-639.

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title = "Site selectivity in the reactions of nucleophiles with [Ru5C(CO)15]: X-ray analysis of [Ru5C(CO)14(µ-η2-MeCO)(AuPPh3)] and [Ru5C(CO)13(η5-C5H5)(AuPPh3)], the first high nuclearity cyclopentadienylruthenium cluster",

abstract = "The cluster [Ru5C(CO)15] reacts with LiMe, followed by [Ph3PAu][Cl], to give [Ru5C(CO)14(µ-η2-MeCO)(AuPPh3)] while reaction with NaC5H5, followed by [Ph3PAu][ClO4], gives [Ru5C(CO)13(η5-C5H5)(AuPPh3)]; X-ray analysis has confirmed that the nucleophile has attacked a carbonyl ligand in the former case but a metal centre in the latter.",

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AB - The cluster [Ru5C(CO)15] reacts with LiMe, followed by [Ph3PAu][Cl], to give [Ru5C(CO)14(µ-η2-MeCO)(AuPPh3)] while reaction with NaC5H5, followed by [Ph3PAu][ClO4], gives [Ru5C(CO)13(η5-C5H5)(AuPPh3)]; X-ray analysis has confirmed that the nucleophile has attacked a carbonyl ligand in the former case but a metal centre in the latter.

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