Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 3962-3969 |
| Number of pages | 8 |
| Journal | European Journal of Inorganic Chemistry |
| Volume | 2019 |
| Issue number | 36 |
| Early online date | 19 Aug 2019 |
| DOIs | |
| Publication status | Published - 30 Sep 2019 |
Keywords
- Calcium
- Chemical vapor deposition
- Single source precursors
- Structure elucidation
- Sulfides
ASJC Scopus subject areas
- Inorganic Chemistry
Cite this
Single Source Precursors for Calcium Sulfide (CaS) Deposition. / Kubiak, Peter; Johnson, Andrew; Cameron, Petra; Kociok-Kohn, Gabriele.
In: European Journal of Inorganic Chemistry, Vol. 2019, No. 36, 30.09.2019, p. 3962-3969.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Single Source Precursors for Calcium Sulfide (CaS) Deposition
AU - Kubiak, Peter
AU - Johnson, Andrew
AU - Cameron, Petra
AU - Kociok-Kohn, Gabriele
PY - 2019/9/30
Y1 - 2019/9/30
N2 - Here we describe preliminary studies into the synthesis structural characterisation and thermal properties of a family of calcium xanthate precursors for application in the deposition of CaS thin films. The straightforward, low-temperature syntheses are detailed along with characterisation of the resulting compounds by 1H and 13C NMR and elemental analysis. Solid state molecular structures of all compounds, obtained from single-crystal X-ray diffraction, are presented and discussed in detail. The decomposition behaviour of the precursors has been probed through TGA, TGA-MS and thermal annealing experiments, indicating that the compounds decompose cleanly into CaS.
AB - Here we describe preliminary studies into the synthesis structural characterisation and thermal properties of a family of calcium xanthate precursors for application in the deposition of CaS thin films. The straightforward, low-temperature syntheses are detailed along with characterisation of the resulting compounds by 1H and 13C NMR and elemental analysis. Solid state molecular structures of all compounds, obtained from single-crystal X-ray diffraction, are presented and discussed in detail. The decomposition behaviour of the precursors has been probed through TGA, TGA-MS and thermal annealing experiments, indicating that the compounds decompose cleanly into CaS.
KW - Calcium
KW - Chemical vapor deposition
KW - Single source precursors
KW - Structure elucidation
KW - Sulfides
UR - http://www.scopus.com/inward/record.url?scp=85071884642&partnerID=8YFLogxK
U2 - 10.1002/ejic.201900550
DO - 10.1002/ejic.201900550
M3 - Article
VL - 2019
SP - 3962
EP - 3969
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 36
ER -