Single Source Precursors for Calcium Sulfide (CaS) Deposition

Peter S. Kubiak; Andrew L. Johnson; Petra J. Cameron; Gabriele Kociok-Köhn

doi:10.1002/ejic.201900550

Single Source Precursors for Calcium Sulfide (CaS) Deposition

Peter S. Kubiak, Andrew L. Johnson, Petra J. Cameron, Gabriele Kociok-Köhn

Material and Chemical Characterisation Facility (MC)

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Abstract

Here we describe preliminary studies into the synthesis structural characterisation and thermal properties of a family of calcium xanthate precursors for application in the deposition of CaS thin films. The straightforward, low-temperature syntheses are detailed along with characterisation of the resulting compounds by ¹H and ¹³C NMR and elemental analysis. Solid state molecular structures of all compounds, obtained from single-crystal X-ray diffraction, are presented and discussed in detail. The decomposition behaviour of the precursors has been probed through TGA, TGA-MS and thermal annealing experiments, indicating that the compounds decompose cleanly into CaS.

Original language	English
Pages (from-to)	3962-3969
Number of pages	8
Journal	European Journal of Inorganic Chemistry
Volume	2019
Issue number	36
Early online date	19 Aug 2019
DOIs	https://doi.org/10.1002/ejic.201900550
Publication status	Published - 30 Sept 2019

Bibliographical note

Funding Information:
This work was funded by the UK Engineering and Physical Sciences Research Council (EPSRC) via the Centre for Doctoral Training in New and Sustainable PV, EP/L01551X/1 (P. S. K.).

Publisher Copyright:
© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

Calcium
Chemical vapor deposition
Single source precursors
Structure elucidation
Sulfides

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/ejic.201900550

ejic.201900550R3.PDF
This is the peer reviewed version of the following article: Kubiak, P. S., Johnson, A. L., Cameron, P. J. and Kociok‐Köhn, G. (2019), Single Source Precursors for Calcium Sulfide (CaS) Deposition. Eur. J. Inorg. Chem., 2019: 3962-3969, which has been published in final form at https://doi.org/10.1002/ejic.201900550. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Accepted author manuscript, 1.74 MBLicence: Unspecified

Cite this

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title = "Single Source Precursors for Calcium Sulfide (CaS) Deposition",

abstract = "Here we describe preliminary studies into the synthesis structural characterisation and thermal properties of a family of calcium xanthate precursors for application in the deposition of CaS thin films. The straightforward, low-temperature syntheses are detailed along with characterisation of the resulting compounds by 1H and 13C NMR and elemental analysis. Solid state molecular structures of all compounds, obtained from single-crystal X-ray diffraction, are presented and discussed in detail. The decomposition behaviour of the precursors has been probed through TGA, TGA-MS and thermal annealing experiments, indicating that the compounds decompose cleanly into CaS.",

keywords = "Calcium, Chemical vapor deposition, Single source precursors, Structure elucidation, Sulfides",

author = "Kubiak, {Peter S.} and Johnson, {Andrew L.} and Cameron, {Petra J.} and Gabriele Kociok-K{\"o}hn",

note = "Funding Information: This work was funded by the UK Engineering and Physical Sciences Research Council (EPSRC) via the Centre for Doctoral Training in New and Sustainable PV, EP/L01551X/1 (P. S. K.). Publisher Copyright: {\textcopyright} 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

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language = "English",

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pages = "3962--3969",

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TY - JOUR

T1 - Single Source Precursors for Calcium Sulfide (CaS) Deposition

AU - Kubiak, Peter S.

AU - Johnson, Andrew L.

AU - Cameron, Petra J.

AU - Kociok-Köhn, Gabriele

N1 - Funding Information: This work was funded by the UK Engineering and Physical Sciences Research Council (EPSRC) via the Centre for Doctoral Training in New and Sustainable PV, EP/L01551X/1 (P. S. K.). Publisher Copyright: © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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Y1 - 2019/9/30

N2 - Here we describe preliminary studies into the synthesis structural characterisation and thermal properties of a family of calcium xanthate precursors for application in the deposition of CaS thin films. The straightforward, low-temperature syntheses are detailed along with characterisation of the resulting compounds by 1H and 13C NMR and elemental analysis. Solid state molecular structures of all compounds, obtained from single-crystal X-ray diffraction, are presented and discussed in detail. The decomposition behaviour of the precursors has been probed through TGA, TGA-MS and thermal annealing experiments, indicating that the compounds decompose cleanly into CaS.

AB - Here we describe preliminary studies into the synthesis structural characterisation and thermal properties of a family of calcium xanthate precursors for application in the deposition of CaS thin films. The straightforward, low-temperature syntheses are detailed along with characterisation of the resulting compounds by 1H and 13C NMR and elemental analysis. Solid state molecular structures of all compounds, obtained from single-crystal X-ray diffraction, are presented and discussed in detail. The decomposition behaviour of the precursors has been probed through TGA, TGA-MS and thermal annealing experiments, indicating that the compounds decompose cleanly into CaS.

KW - Calcium

KW - Chemical vapor deposition

KW - Single source precursors

KW - Structure elucidation

KW - Sulfides

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

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ER -

Single Source Precursors for Calcium Sulfide (CaS) Deposition

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Avance 300 MHz Nuclear Magnetic Resonance (NMR) Spectrometer (1South)

Dual source (Cu and Mo) Single Crystal Diffractometer (SuperNova)

Thermogravimetric Analyser coupled to a Mass Spectrometer (TGA-MS)

Cite this

Single Source Precursors for Calcium Sulfide (CaS) Deposition

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Equipment

Avance 300 MHz Nuclear Magnetic Resonance (NMR) Spectrometer (1South)

Dual source (Cu and Mo) Single Crystal Diffractometer (SuperNova)

Thermogravimetric Analyser coupled to a Mass Spectrometer (TGA-MS)

Cite this