Single Source Precursors for Calcium Sulfide (CaS) Deposition

Peter Kubiak, Andrew Johnson, Petra Cameron, Gabriele Kociok-Kohn

Research output: Contribution to journal › Article

Abstract

Here we describe preliminary studies into the synthesis structural characterisation and thermal properties of a family of calcium xanthate precursors for application in the deposition of CaS thin films. The straightforward, low-temperature syntheses are detailed along with characterisation of the resulting compounds by 1H and 13C NMR and elemental analysis. Solid state molecular structures of all compounds, obtained from single-crystal X-ray diffraction, are presented and discussed in detail. The decomposition behaviour of the precursors has been probed through TGA, TGA-MS and thermal annealing experiments, indicating that the compounds decompose cleanly into CaS.
Original languageEnglish
Number of pages8
JournalEuropean Journal of Inorganic Chemistry
Early online date19 Aug 2019
DOIs
Publication statusE-pub ahead of print - 19 Aug 2019

Keywords

  • Calcium
  • Chemical vapor deposition
  • Single source precursors
  • Structure elucidation
  • Sulfides

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Single Source Precursors for Calcium Sulfide (CaS) Deposition. / Kubiak, Peter; Johnson, Andrew; Cameron, Petra; Kociok-Kohn, Gabriele.

In: European Journal of Inorganic Chemistry, 19.08.2019.

Research output: Contribution to journal › Article

Kubiak, P, Johnson, A, Cameron, P & Kociok-Kohn, G 2019, 'Single Source Precursors for Calcium Sulfide (CaS) Deposition', European Journal of Inorganic Chemistry. https://doi.org/10.1002/ejic.201900550
Kubiak P, Johnson A, Cameron P, Kociok-Kohn G. Single Source Precursors for Calcium Sulfide (CaS) Deposition. European Journal of Inorganic Chemistry. 2019 Aug 19. https://doi.org/10.1002/ejic.201900550
Kubiak, Peter ; Johnson, Andrew ; Cameron, Petra ; Kociok-Kohn, Gabriele. / Single Source Precursors for Calcium Sulfide (CaS) Deposition. In: European Journal of Inorganic Chemistry. 2019.
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