Single- And double-helices of α,α′-dibenzylaminotripyrrin: solution and solid state studies

Kento Ueta, Masataka Umetani, Atsuhiro Osuka, G. Dan Pantoş, Takayuki Tanaka

Research output: Contribution to journalArticlepeer-review

9 Citations (SciVal)

Abstract

The dimeric association of α,α′-di(benzylamino)tripyrrin in chloroform was found to be 40 times less effective than that of previously reported α,α′-dianilinotripyrrin, which, however, led us to observe the co-crystal structure of single and double helix forms. Attachment of chiral phenylethylamines on the same tripyrrin platform was also performed to induce helical chirality.

Original languageEnglish
Pages (from-to)2617-2620
Number of pages4
JournalChemical Communications
Volume57
Issue number21
Early online date2 Feb 2021
DOIs
Publication statusPublished - 14 Mar 2021

Bibliographical note

Funding Information:
The work at Kyoto was supported by JSPS KAKENHI Grant Number (JP20K05463). K. U. and M. U. acknowledge JSPS Fellowships for Young Scientists. T. T. acknowledges financial support from the TOBEMAKI Scholarship Foundation, Murata Science Foundation and Izumi Science and Technology Foundation. G. D. P. thanks the EPSRC and University of Bath for financial support.

Publisher Copyright:
© The Royal Society of Chemistry 2021.

Copyright:
Copyright 2021 Elsevier B.V., All rights reserved.

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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